The Law of Cosines can be used to find the angle measures of an isosceles triangle when the side lengths are known. Specifically, if a = BC, b = CA, and c = AB, the formula cos(C) = (a² + b² - c²) / 2ab allows for the calculation of angle C. This method requires knowledge of the two equal sides of the isosceles triangle. Without at least one additional piece of information, such as another side length or an angle measure, the angle measures cannot be determined. Therefore, understanding the side lengths is crucial for applying this formula effectively.