If the vapor pressure of a component exceeds the system pressure, it indicates that the component will exist entirely in the vapor phase, with no liquid phase present. If a liquid phase is already present, it will start to boil away as the vapor pressure increases. When the partial pressure of a component matches its vapor pressure, any additional mass will be in the vapor phase, eliminating the liquid phase. This relationship highlights the critical balance between vapor pressure and system pressure in determining phase states. Understanding these principles is essential for applications involving phase transitions in various scientific fields.