fzero said:
Right, just keep in mind that this is true for an ideal case of free-particles that are isolated from interacting with another system. This is typically the case for how the asymptotic states are defined for some high-energy scattering amplitude, but other common examples from condensed matter are very different.
I was still dealing with free-particles so I only wanted to interpret the expression as creating a two particle state. For that to be the case, we should really put the operators at different points or use time or normal ordering to avoid the case where a creation operator cancels against an annihilation operator.
However, it is true that perturbative analysis of interacting theories also involves computing matrix elements of operator products. For example, in ##\phi^4## theory there is a tree-level term (schematically)
$$ \langle 3,4 | \phi^4 | 1,2\rangle.$$
As a scattering process, we have an input state with particles 1 and 2 (and associated momenta,etc) that enter the interaction region, interact according to the lowest order process, and then particles 3 and 4 are the output that are detected in the future. Again, instead of "##\phi^4##" we'd have a time-ordered product to keep this better defined. If we expand in the annihilation and creation operators, we'd also see that only the terms with equal numbers of annihilation and creation operators will appear since we are keeping the number of particles in the initial and final states equal to 2.
OK I should perhaps leave the interaction stuff alone for a while, seems like a bit of a rabbit hole that I can disappear down another time. Going back to earlier, I've got the SU(2) group generators:
$$ \sigma^{1} = \begin{pmatrix} 0 & 1 \\ 1 & 0\end{pmatrix} \hspace{1 cm}
\sigma^{2} = \begin{pmatrix} 0 & -i \\ i & 0\end{pmatrix} \hspace{1 cm}
\sigma^{3} = \begin{pmatrix} 1 & 0 \\ 0 & -1\end{pmatrix} $$
So if I define
$$ \sigma^{+} = \frac{1}{2}(\sigma^{1} + i\sigma^{2}) = \frac{1}{2}\begin{pmatrix} 0 & 1 \\ 1 & 0\end{pmatrix} + \frac{i}{2} \begin{pmatrix} 0 & -i \\ i & 0\end{pmatrix}
= \begin{pmatrix} 0 & \frac{1}{2} \\ \frac{1}{2} & 0\end{pmatrix} + \begin{pmatrix} 0 & \frac{1}{2}\\ \frac{-1}{2} & 0\end{pmatrix}
= \begin{pmatrix} 0 & 1 \\ 0 & 0\end{pmatrix}
$$
$$ \sigma^{-} = \frac{1}{2}(\sigma^{1} - i\sigma^{2}) = \frac{1}{2}\begin{pmatrix} 0 & 1 \\ 1 & 0\end{pmatrix} - \frac{i}{2} \begin{pmatrix} 0 & -i \\ i & 0\end{pmatrix}
= \begin{pmatrix} 0 & \frac{1}{2} \\ \frac{1}{2} & 0\end{pmatrix} - \begin{pmatrix} 0 & \frac{1}{2}\\ \frac{-1}{2} & 0\end{pmatrix}
= \begin{pmatrix} 0 & 0 \\ 1 & 0\end{pmatrix}
$$
I can have these operate on my weak isospin doublet ##\psi_{L}## to get
$$ \sigma^{+} \psi_{L} = \begin{pmatrix} 0 & 1 \\ 0 & 0\end{pmatrix} \begin{pmatrix} \nu_{e} \\ e^{-} \end{pmatrix} = \begin{pmatrix} 0 \\ e^{-} \end{pmatrix} = \psi_{e^{-}}
\hspace{1 cm}
\sigma^{-} \psi_{L} = \begin{pmatrix} 0 & 0 \\ 1 & 0\end{pmatrix} \begin{pmatrix} \nu_{e} \\ e^{-} \end{pmatrix} = \begin{pmatrix} \nu_{e} \\ 0 \end{pmatrix} = \psi_{\nu_{e}}
$$
The attached image has an expression for the 'currents' ##J^{\mu+} = \overline{\psi}_{e^{-}} \gamma^{\mu} (1 - \gamma^{5}) \psi_{\nu_{e}}## and
##J^{\mu-} = \overline{\psi}_{\nu_{e}} \gamma^{\mu} (1 - \gamma^{5}) \psi_{e^{-}}##. So let's see if I can interpret these objects any better now...
##J^{\mu+}## is bookended by ##\overline{\psi}_{e^{-}}## and ##\psi_{\nu_{e}}##... so I have a ##\nu_{e}## creation operator (for every momentum state) and a ##e^{-}## annihilation operator acting on the vacuum at this ##(t, \textbf{x})##? So this expression represents or relates to a charged-current weak interaction with a ##W^{-}## boson emitted?
And there's also ##\gamma^{\mu} (1 - \gamma^{5})## sandwiched in the middle... The ##(1 - \gamma^{5})## ensures we just deal with the left-handed part of the field it acts on I think, (##\psi_{L} = (\frac{1 - \gamma^{5}}{2}) \psi##, not obvious to me how that equation works but for now I'll just believe it)... and that just leaves the ##\gamma^{\mu}## in there, which I'm not sure of the significance of?