What is the Oxidation Number of Pb in Pb(O)2?

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Discussion Overview

The discussion revolves around determining the oxidation number of lead (Pb) in the compound Pb(O)2. Participants are examining the oxidation states of elements in this compound, with a focus on the implications of whether oxygen is treated as a peroxide or not. The scope includes homework-related reasoning and chemical nomenclature.

Discussion Character

  • Homework-related, Debate/contested, Conceptual clarification

Main Points Raised

  • One participant suggests that the oxidation number of Pb is +2 and O is -1, treating it as a peroxide.
  • Another participant asserts that PbO2 is not a peroxide, implying a different oxidation state for oxygen.
  • A third participant recalls that lead dioxide has been misleadingly referred to as "lead peroxide" in the past, indicating potential confusion in nomenclature.
  • A later reply emphasizes that oxygen should be considered as having an oxidation state of -2, prompting a calculation of Pb's oxidation state based on this assumption.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the oxidation state of oxygen in Pb(O)2, leading to differing conclusions about the oxidation state of lead. The discussion remains unresolved regarding the correct treatment of oxygen in this context.

Contextual Notes

There are limitations in the discussion regarding the definitions and nomenclature of compounds, as well as the historical context of naming conventions that may affect the understanding of oxidation states.

ThatDude
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Homework Statement


The problem is:

Find the oxidation number of each element in the compound: Pb(O)2

I said oxidation number of Pb = x, O = -1 since this is a peroxide, therefore oxidation number of Pb is plus 2. However, the solution manual says O is -2 and thus Pb is 2.

But elsewhere, for the problem BaO2, they say the oxidation number of O is -1 and Ba is +2.

I'm confused.

Homework Equations

The Attempt at a Solution

 
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PbO2 is not a peroxide.
 
Not clear whether it is the manual or you who is saying Pb in PbO2 is +2 but now hopefully not.

I have a vague recollection that lead dioxide did sometimes get improperly and misleadingly called "lead peroxide",
probably before chemical nomenclature was formalised and the name still hangs around.
 
Borek is 100% right, it ain't a peroxide ... Hint: Oxy = -2, Calculate oxidation state of Pb.
 

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