What is the Oxidation Number of Pb in Pb(O)2?

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In summary, there is confusion about the oxidation numbers for lead and oxygen in the compounds Pb(O)2 and BaO2. While some sources claim oxygen has an oxidation number of -1 in both compounds, others say it is -2 in Pb(O)2 and -1 in BaO2. It is important to note that PbO2 is not a peroxide, despite its name. The correct oxidation number for lead in PbO2 is +2, while oxygen has an oxidation number of -2.
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ThatDude
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Homework Statement


The problem is:

Find the oxidation number of each element in the compound: Pb(O)2

I said oxidation number of Pb = x, O = -1 since this is a peroxide, therefore oxidation number of Pb is plus 2. However, the solution manual says O is -2 and thus Pb is 2.

But elsewhere, for the problem BaO2, they say the oxidation number of O is -1 and Ba is +2.

I'm confused.

Homework Equations

The Attempt at a Solution

 
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  • #2
PbO2 is not a peroxide.
 
  • #3
Not clear whether it is the manual or you who is saying Pb in PbO2 is +2 but now hopefully not.

I have a vague recollection that lead dioxide did sometimes get improperly and misleadingly called "lead peroxide",
probably before chemical nomenclature was formalised and the name still hangs around.
 
  • #4
Borek is 100% right, it ain't a peroxide ... Hint: Oxy = -2, Calculate oxidation state of Pb.
 

Related to What is the Oxidation Number of Pb in Pb(O)2?

1. What is an oxidation number?

An oxidation number is a number assigned to an atom in a chemical compound that represents the number of electrons that atom has gained or lost. It is used to track the flow of electrons in chemical reactions.

2. How is an oxidation number determined?

The oxidation number is determined based on the rules established by the periodic table. In general, elements in their elemental form have an oxidation number of 0, while the oxidation number of an ion is equal to its charge. Additionally, some elements have a fixed oxidation number, such as oxygen (-2) and hydrogen (+1).

3. What is the purpose of knowing an element's oxidation number?

Knowing an element's oxidation number is important in predicting and balancing chemical reactions. It also helps in identifying the type of bond formed between atoms (ionic, covalent, or metallic).

4. How does oxidation number relate to oxidation and reduction?

Oxidation number is closely related to oxidation and reduction, which are chemical reactions involving the transfer of electrons. An increase in oxidation number signifies oxidation, while a decrease signifies reduction.

5. Can an element have multiple oxidation numbers?

Yes, an element can have multiple oxidation numbers depending on the compound it is in. For example, iron can have an oxidation number of +2 or +3 in different compounds. The rules for determining oxidation numbers can help in determining the correct one.

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