Where Is the Error in My Understanding of the Boltzmann Distribution?

AI Thread Summary
The discussion centers on the misunderstanding of the Boltzmann distribution, particularly regarding the proportionality of energy terms. The initial expectation of proportionality to E^-1/2 is corrected by recognizing that the distribution f_p is based on the magnitude of momentum p, leading to an extra factor of p^2 in the integration measure. This factor results in the observed proportionality to E^1/2 in the Maxwell distribution. Additionally, the absence of the E^1/2 factor in the potential energy distribution of gas in a vertical tube is attributed to the dimensional considerations of the system. Clarification of these relationships enhances the understanding of the distribution's derivation and its implications.
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Why do you expect proportionality to E^-1/2 ? What would be your full expression for the Maxwell distribution and why?
 
I expect that p^2/(2m)=E, so p=(2Em)^1/2 so
dp/dE = proportional to E^-1/2
Maybe px, py, pz, demand a different formula?
 
I suspect the following, although i haven't really analyzed it in detail:

The distribution f_p used in that calculation is the distribution over the magnitude of p, not the distribution over the three components px, py, pz. So there is an extra factor p^2 due to the integration measure p^2 dp dphi dtheta, and then you integrates over phi/theta. The extra factor p^2 causes an extra factor E , that turns your E^-1/2 into the E^1/2 in the formula.
 
torquil said:
I suspect the following, although i haven't really analyzed it in detail:

The distribution f_p used in that calculation is the distribution over the magnitude of p, not the distribution over the three components px, py, pz. So there is an extra factor p^2 due to the integration measure p^2 dp dphi dtheta, and then you integrates over phi/theta. The extra factor p^2 causes an extra factor E , that turns your E^-1/2 into the E^1/2 in the formula.
Yes, now I see that it is so. Above in my link is calculation with distrubution of speed v. If I use dn/dv and dv/dE, and f(v) the above is clear.

It was also unclear to me, that distribution of potential energy of gas in vertical tube has not factor E^1/2. Because this factor is a consequence of three dimensions.
Is it OK comparision, or it should be something better for a distribution without additional factor E^1/2?
 
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