Why are some salts colored even with all electrons paired?

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Discussion Overview

The discussion revolves around the phenomenon of colored salts, specifically addressing why some salts exhibit color despite having all their electrons paired. Examples mentioned include potassium dichromate, potassium permanganate, and silver bromide/iodide. The scope includes theoretical explanations and the underlying mechanisms of color in salts.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification

Main Points Raised

  • Some participants assert that unpaired electrons are not necessary for a salt to be colored.
  • Others propose that the color observed in certain salts, such as potassium permanganate (KMnO4), is due to "charge transfer" effects, which can result in bright and intense colors even with paired electrons.
  • A participant requests further explanation of the charge transfer effect and the types of salts in which this effect may be observed.

Areas of Agreement / Disagreement

Participants express differing views on the necessity of unpaired electrons for color in salts, indicating a lack of consensus on the mechanisms involved.

Contextual Notes

The discussion does not clarify the specific conditions or definitions under which charge transfer effects occur, nor does it resolve the underlying mechanisms contributing to the color of the salts mentioned.

bsrishu
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why some salts are coloured although all the electrons are paired in it?
Ex: potassium dichromate, potassium permanganate, silver bromide/iodide.
 
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You don't need unpaired electrons to have a colored salt.
 
Its because of "charge transfer" that some salts inspite of having paired electrons have bright intense colour like KMnO4
 
can you please explain this charge transfer effect, and in which type of this will be observed?
 

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