Why can U be expanded in terms of T and V?

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The discussion focuses on the expansion of internal energy (U) in terms of temperature (T) and volume (V) when expressing the differential of entropy (dS). The mathematical relationship is defined by the equation dU/dT(V) + dU/dV(T), which represents the total differential of U with respect to the coordinates (T, V). This expansion does not alter the meaning of the expression, as it adheres to the principles of thermodynamics. The conversation also touches on the number of intensive properties necessary to define the state of a single-phase material with constant composition.

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thegirl
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when expressing dS as a function of dV and dT, dU was expanded out as you can see in the screenshot below, is there a mathematical rule which allows this? does the fact that the internal energy is expanded out change the meaning of the expression?
Screen Shot 2016-03-24 at 17.45.17.png
 
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How many intensive properties are required to specify the state of a single phase material of constant composition?
 
thegirl said:
when expressing dS as a function of dV and dT, dU was expanded out as you can see in the screenshot below, is there a mathematical rule which allows this? does the fact that the internal energy is expanded out change the meaning of the expression?View attachment 97881
dU/dT(V)+dU/dV(T) is the differential of U with the coordinated (T,V)
 
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