Cell walls in herbs become brittle when dried due to the loss of water, which is essential for maintaining turgor pressure within the cells. Turgor pressure is the force exerted by water inside the cell that keeps it firm and rigid. When herbs are fresh, the water content helps to keep the cells turgid, providing structural integrity. Upon drying, the water evaporates, leading to a decrease in turgor pressure, causing the cells to wilt and the cell walls to become fragile. This process highlights the critical role of water in preserving the structural properties of plant cells.