Why do most reagents have potassium instead of sodium?

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Potassium is commonly used as the cation in various reagents, such as potassium permanganate, potassium chlorate, potassium nitrate, and potassium iodide, despite its higher cost compared to sodium. While sodium salts are available and frequently used in laboratory settings, such as sodium iodide, potassium salts are preferred in certain applications due to factors like solubility, availability, and reactivity differences. For instance, sodium chlorite is utilized in commercial bleach instead of its potassium counterpart. The choice between potassium and sodium salts often hinges on these practical considerations rather than cost alone.
ShawnD
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Many reagents have potassium as the cation instead of sodium. Permanganate is always potassium permanganate. Chlorate is always potassium chlorate. Nitrate is always potassium nitrate. Iodide is potassium iodide.
If potassium costs more money, why is it used in everything?
 
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You can usually get the sodium salts too. We use sodium iodide in the lab all the time, but rarely KI. Also, sodium chlorite is used in commercial bleach, not potassium. Sometimes its a solubility issue, sometimes it's just availability. There is sometimes a reactivity difference as well.
 
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