Using complex identities for sin(pi*k/3) in Fourier series calculations can be challenging, as demonstrated by the difficulty in applying the fundamental theorem of calculus. The theorem states that the integral of a function can be evaluated using its antiderivative. To simplify the calculations, it's suggested to multiply by the term e^(-j*pi*k/3), which can help in managing the exponential terms in the final answer. This approach integrates elemental algebra and complex analysis to facilitate the process. Understanding these steps is crucial for effective Fourier series computations.