Why was the F block of the periodic table created?

AI Thread Summary
The discussion centers on the F block of the periodic table, which includes elements that are often artificially synthesized. The primary motivation for synthesizing these elements is scientific curiosity, although practical applications also play a significant role. Notably, while many lanthanides occur naturally, Promethium is exclusively synthetic and radioactive. The conversation highlights the widespread use of f-block elements in modern technology, such as in fluorescent and LED lamps, smoke detectors, and various electronic devices. Specific elements like Neodymium and Gadolinium are mentioned for their roles in lasers, magnets, and medical imaging. The historical context of these elements is also touched upon, with references to their synthesis during the Manhattan Project and the origins of their names, which relate to their discovery in Sweden. The term "rare earth" is discussed as a misleading label, given that these elements are relatively abundant in the Earth's crust.
nineteen
Messages
68
Reaction score
12
Basically, the F block is a series in the periodic table that consist of elements that are artificially synthesized. My question is, why were these elements synthesized? What was the need of synthesizing such elements?
 
Chemistry news on Phys.org
I am confident others with expertise in this area will provide specific scientific reasons, but arguably the underlying one is the same that accounts for all science - Curiosity.
 
  • Like
Likes nineteen
Ophiolite said:
I am confident others with expertise in this area will provide specific scientific reasons, but arguably the underlying one is the same that accounts for all science - Curiosity.
Thank you for the answer.
 
nineteen said:
Basically, the F block is a series in the periodic table that consist of elements that are artificially synthesized.

Nope. All lanthanides and some actinides are perfectly 'natural'.

My question is, why were these elements synthesized? What was the need of synthesizing such elements?

I am with Ophiolite on this one.
 
Borek said:
Nope. All lanthanides and some actinides are perfectly 'natural'.
My research is on Lanthanides and to very slightly correct Borek's statement, Promethium (Pm), the 5th element in the lanthanide series, is naturally unavailable. It can only be artificially synthesized and is radioactive.

nineteen said:
Basically, the F block is a series in the periodic table that consist of elements that are artificially synthesized. My question is, why were these elements synthesized? What was the need of synthesizing such elements?
By the way, look up to the ceiling in some building. If you see a fluorescent lamp or LED lamp, the chance is, there are f-block elements in it. Specifically, Ce, Eu, and Tb for fluorescent lamps, and Ce for LED lamps. (Just to note that these days, there are increasingly more "warm" fluorescent lamps and LED lamps, which the composing elements are different.) If you have a cellphone or iphone or whatever phone with a camera, there's a little yellowish device next to it that you can use it for flashlight. Most likely, it is made out of Ce:YAG on a blue emitting diode.

If I recall correctly, smoke detectors contain Americium (I forgot the specific isotope), a crucial element for the device to work. There are also depleted Uranium ammunition and armor plates. Neodymium is commonly used in lasers and magnets. Gadolinium compounds are used as an imaging agent for MRIs.

Basically, they are used everywhere.
 
  • Like
Likes Ygggdrasil, nineteen and Ophiolite
HAYAO said:
My research is on Lanthanides and to very slightly correct Borek's statement, Promethium (Pm), the 5th element in the lanthanide series, is naturally unavailable. It can only be artificially synthesized and is radioactive.

My bad, completely forgot about it :frown:
 
nineteen said:
Basically, the F block is a series in the periodic table that consist of elements that are artificially synthesized. My question is, why were these elements synthesized? What was the need of synthesizing such elements?
The first non-natural actinide elements where synthesized in the Manhattan atomic bomb project. Namely Plutonium was used in the "Fat man" bomb droped on Nagasaki.
 
  • Like
Likes nineteen
HAYAO said:
My research is on Lanthanides and to very slightly correct Borek's statement, Promethium (Pm), the 5th element in the lanthanide series, is naturally unavailable. It can only be artificially synthesized and is radioactive.By the way, look up to the ceiling in some building. If you see a fluorescent lamp or LED lamp, the chance is, there are f-block elements in it. Specifically, Ce, Eu, and Tb for fluorescent lamps, and Ce for LED lamps. (Just to note that these days, there are increasingly more "warm" fluorescent lamps and LED lamps, which the composing elements are different.) If you have a cellphone or iphone or whatever phone with a camera, there's a little yellowish device next to it that you can use it for flashlight. Most likely, it is made out of Ce:YAG on a blue emitting diode.

If I recall correctly, smoke detectors contain Americium (I forgot the specific isotope), a crucial element for the device to work. There are also depleted Uranium ammunition and armor plates. Neodymium is commonly used in lasers and magnets. Gadolinium compounds are used as an imaging agent for MRIs.

Basically, they are used everywhere.
Wow! Thank you so much for the information. Your comment is very helpful thank you again.
 
DrDu said:
The first non-natural actinide elements where synthesized in the Manhattan atomic bomb project. Namely Plutonium was used in the "Fat man" bomb droped on Nagasaki.
Thank you for commenting, it is very informative.
 
  • #10
Fun factoid: four of the lanthanides are named after the same town in Sweden, the location of the mine that produced the ores from which they were first discovered.

747px-ASM_ytterbymine.jpg


(source: Wikipedia)
 

Attachments

  • 747px-ASM_ytterbymine.jpg
    747px-ASM_ytterbymine.jpg
    134.5 KB · Views: 755
  • Like
Likes BillTre, nineteen and HAYAO
  • #11
jtbell said:
Fun factoid: four of the lanthanides are named after the same town in Sweden, the location of the mine that produced the ores from which they were first discovered.

(Pic here)

(source: Wikipedia)

And because these minerals contained rather low content of lanthanide ions and was also difficult to separate each other due to similar chemical properties, they were named "rare-earth" (lanthanides + scandium and yttrium). This is a very misleading name because rare-earth elements are rather plentiful in Earth's crust.Fun fact: "Rare-Earth's" in Japanese is "希土類 (kidorui)", however it used to be written "稀土類 (also read kidorui)". The first letter of the latter form literally only means "rare". However, it was changed later into the first letter of the former form, which can mean "rare", "hope", or "noble". I am speculating that this is because they realized the importance of these elements after their properties were studied.

(Note to moderators: I believe using foreign language was appropriate in this case.)
 
  • Like
Likes BillTre, nineteen and DrDu
  • #12
Further to the etymological point. At the time the term 'rare earth' was coined, 'earth' was sometimes used as a synonym for an oxide, which was the form in which most (well, some... i think the historical issue may be a bit muddled, or maybe it is just my recollection that is) rare Earth's (at the time) were found. Just one of those quirky linguistic things.

diogenesNY
 
  • Like
Likes BillTre
Back
Top