What is Molecular: Definition and 580 Discussions

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. B

    [PoM] Rotational and vibrational heat capacity

    Hi guis, i need your help... 1. Homework Statement Evaluate the rotational and vibrational contributions to the heat capacity of a gas of DBr (D=deuterium, Br=mixture at 50% of 79Br and 81Br) at 380 K temperature, knowing that the bond distance is 1.41 Å and the vibration frequency of 1H79Br...
  2. Mark Harder

    Anti-hydrogen molecular spectra?

    I'm not a molecular physicist, so my speculations are bound to be somewhat naive. I'm only hoping to initiate some discussion around the subject, which I thought might be interesting to all. Now that the electronic absorption spectrum of the atomic anti-hydrogen 1s->2s electronic transition...
  3. Konte

    I Molecular Hamiltonian - Ammonia

    Hello everybody, The general expression of molecular Hamiltonian operator for any molecule is: $$\hat{H} = \hat{T}_n+\hat{T}_e+\hat{V}_{ee}+\hat{V}_{nn}+\hat{V}_{en}+\hat{f}_{spin-orbit} $$ where: ##\hat{T}## correspond to kinetic energy operator ##\hat{V}## correspond to potential energy...
  4. Cloud Wolf

    A Determining molecular resonance frequencies

    I have been searching for ways to calculate resonance frequencies of complex molecules. I know that doing so is extremely complex, especially if that molecule contains many elements, but perhaps it could be feasible to target a specific component of a large molecule, such as a nucleus in a cell...
  5. E

    Standard corrections to GFE for uni and bi molecular rxns

    Hello everyone. I have a weird question regarding the calculation of free energy changes in a multi-step mechanism. Now, if you have a bunch of calculated free energies in gas phase at 1 atm (say, from an electronic structure program) and you want to model in solvent, you need to get them in a...
  6. donaldparida

    Dot between the molecular formula of compounds

    I have seen many instances of molecular formulas of two or more compounds with a dot between two adjacent molecular formulas like CuSO4.10H20, CaCO3.MgCO3, K2SO4.Al2(SO4)3.24H20 and so on. What does the dot indicate?
  7. L

    Chemistry Chemistry: Molecular Iodine and Atomic Iodine

    So I just had a question about calculating moles atomic iodine when you have the moles of molecular iodine. In the chemical equation IO3-(aq) + I-(aq) + H+(aq) = I2(aq) + H2O(l) Would the moles of atomic iodine be equal to the moles of the molecular iodine? or would the moles of atomic iodine...
  8. dexterdev

    A Can a molecular dynamics simulation enter a limit cycle?

    In my rough understanding Molecular Dynamics using Classical Newtonian mechanics is a 6N dimensional non linear system. 6N dimension because you have 3 position vectors and 3 momentum vectors for each N particles. Nonlinearity because of the terms in force fields. In principle this system can...
  9. J

    A What is the most complex structure you can simulate at home?

    Let's say you have a good personal computer with these characteristics: i7-6700K, 32GB RAM, 256GB SSD, 2 x GTX 970 4GB And let's assume you can run your algorithms, software... for 24 hours. I wonder, if I would be calculating the orbital structure of an hydrogen atom with many electrons...
  10. DrClaude

    Nobel prize: molecular machines

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  11. Edwina Lee

    Misc. Create Molecular Models with Balls & Links - Pros & Cons

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  12. A

    Molecular Biologist with interest in Quantun Biology

    Hello everyone! I am really glad to be part of this group. I hold a Bachelor of Science with Honors in Molecular Biology from the University of Sydney. During the past 10 years, I built a strong career in the business side of research, working as a technical sales consultant, and despite the...
  13. T

    Chemistry Molecular formula of organic compound

    Homework Statement Homework EquationsThe Attempt at a Solution Firstly I tried to find the empirical formula: C : H : O 65.2 : 8.75 : 26.05 (mass) 5.43 : 8.75 : 1.628 (mol) 3.34 : 5.37 : 1 10 : 16 : 3 C10H16O3 This gives a molecular mass of 184. Now with the structure: It has to...
  14. Nate0331

    Electromagnetism and injury -- physical contact at the molecular level....

    So here is my question, and maybe I am not asking it right, but here we go: If electromagnetism prevents me from actually touching anything at a quantum level, how is it that I can get cut by a knife, or get a road rash falling off my bike? If the negative field of electrons that surround...
  15. T

    How does the distance between molecules affect temperature?

    Homework Statement According to the kinetic molecular theory: as the distance between the molecules increases, the temperature of a material decreasesthe rise in temperature of a material occurs because the molecules lose kinetic energywhen the molecules within a gas collide they lose energy...
  16. N

    Electrons energy levels do not change with molecular bonding

    So if energy levels, or eV of electrons, do not change with molecular bonding, how are electrons influencing each other.? In glass, when individual atoms of silicon, sodium, and calcium come together, to form glass, the molecular bonding does not change the energy levels of the electrons for...
  17. kev931210

    Stochastic dynamics and Angular velocity of a molecular motor

    Homework Statement Homework Equations Langevin equation (I included all the equations in the next section.[/B]The Attempt at a Solution I do not know how I can proceed from this point. I'm stuck since I have no information on the drag coefficient. Maybe my approach is wrong, and there may...
  18. V

    What home based solvent might dissolve unknown molecular particles?

    What home based solvent might dissolve an unknown electron microscope seen insoluble particles ? There are some sort of unknown insoluble particles in our water. Does anyone know of any home remedy acid solution (baking soda and vinegar) that might dissolve these particles ? Please keep in...
  19. I

    The molecular switch from welcoming to attacking a pathogen?

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  20. hdp12

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  21. Karan Punjabi

    Does B2 Have a Sigma Molecular Orbital?

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  22. A

    Can Heun's Method Accurately Predict Small Oscillations of a Nitrogen Atom?

    Homework Statement Use the Heun method to compute the period of small oscillations about the equilibrium position of a nitrogen atom. xi = 1.1 Um = 7.37 x0 = 1.2 alpha = 2.287 m = 2.325e-26 Homework Equations [/B] U(x) = Um((1-e^(-alpha(x-x0)))^2 - 1) The Attempt at a Solution I was told to...
  23. Ronie Bayron

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  24. H

    Problem with molecular vibrations

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  25. C

    How to Keep Up with Molecular Orbitals for Intro Chemistry

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  26. M

    Number of molecular hits from air onto a surface

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  27. B

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  28. B

    Chemistry Understanding Simple Molecular Structures in Chemistry

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  29. R

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  30. A

    What is an oscillating molecular dipole defined as?

    Is an oscillating dipole of a molecule the periodic motion of the atoms in the molecule (the oscillating back and forth of a more negatively charged atom and more positively charged atom), or, is an oscillating molecular dipole just oscillations in electron density? I just can't get a clear...
  31. RaulTheUCSCSlug

    Average Speed for Maxwell's Distribution of Molecular Speed

    Using the Maxwell-Boltzmann equation above, there is an example in my book (Giancoli 4th edition p. 481) where they use this to find the average velocity. I understand that it would just be the sum of all the speeds of the molecules divided by the number of molecules. But then I'm having...
  32. S

    Specific Heat and its relevance to Molecular Configuration

    Hello, this is one of the problems in my laboratory manual and it has been killing me. I've been working on this all week. It's due tonight, so hopefully it's not too late... 1. Homework Statement Explain why specific heat is "specific", and how it gives a relative indication of molecular...
  33. MidgetDwarf

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  34. Priyadarshini

    Chemistry Molecular Energy With Relation to Number of Molecules

    Homework Statement Which solid-line curve most accurately represents the distribution of molecular energies in a gas at 500 K if the dotted-line curve represents the corresponding distribution for the same gas at 300 K? Homework Equations - The Attempt at a Solution Not sure how this...
  35. H

    Molecular desgin for a narrow potential surface curve

    Rather a short question, but what kind of design can be used for a narrow potential surface curvature in molecules?
  36. EJC

    Schools Chances of Getting Into Graduate School Ph.D Programs

    I am a rising senior at a small liberal arts college, with an incredibly small (and therefore unrecognized) physics program. I am seeking advice regarding which Ph.D programs are within my reach. I plan on applying to AMO (Atomic, Molecular, and Optics) Ph.D programs with the intention of...
  37. Y

    Study molecular conformation using optical spectroscopy?

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  38. K

    Impact of molecular bonding on therm. neutron cross-sections

    Hi everyone. Most of what I've read on thermal neutron cross sections talks only about what isotope makes up the neutron target. Likewise, all of the cross sections listed on Sigma: http://www.nndc.bnl.gov/sigma/index.jsp?as=9&lib=endfb7.1&nsub=10 ... are broken down just by isotope. However...
  39. S

    Molecular orientation and volume

    In the process for orienting molecular chains, for example dyneema, does the volume of the polymer change? In the process for creating dyneema, the fibers are drawn, heated and elongated. Would this change the volume of fiber? I know the density for dyneema is listed at .97. The density of...
  40. V

    Calculating required amount of molecular sieves for PSA?

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  41. H

    Chemistry Molecular Solid vs Network Covalent Solids

    Homework Statement I'm having trouble figuring out if a solid is a molecular solid or network covalent solid. Classify the following as a network covalent solid or a molecular solid: 1. CO2 2. SiO2 Homework Equations Molecular solid held together by intermolecular forces Covalent network...
  42. S

    Molecular Solids: Primary, Secondary & Van Der Waals Bonds

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  43. jdawg

    What Does Molecular Orbital Theory Say About the Overlap of Atomic Orbitals?

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  44. M

    Molecular Modeling: Geometry Optimization, Vibration Analyses & More

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  45. B

    Molecular Modeling of Fluid Mechanics

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  46. Misha Kuznetsov

    Molecular Hydrogen Ionization

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  47. Seydlitz

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  48. L

    Molecular Hydrogen absorption spectrum

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  49. W

    How Do Orbital Interactions and Sigma Bonds Work in Methane?

    Hello all I have an exam coming up this week but there's something that I don't understand: Let's take methane, for example. If I understand it correctly, the bonding orbitals of carbon are all hybridized to sp³ orbitals and overlap with the 1s orbital of four H atoms. Does the orbital of...
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