Calculating Ionic Radius of Chloride Ion in LiCl (NaCl Structure)

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To calculate the ionic radius of the chloride ion in the NaCl structure with a unit cube length of 5.14 angstroms, it is essential to assume anion-anion contact. In this context, the anion is defined as the negatively charged ion, which is the chloride ion (Cl-). The NaCl structure features a face-centered cubic arrangement where the anions and cations alternate positions. To visualize this, a 3D figure of the NaCl lattice can be helpful, illustrating the arrangement of ions and their interactions. This understanding is crucial for accurately determining the ionic radius based on the unit cell dimensions and the assumption of direct contact between anions.
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Q.The unit cube length of LiCl (NaCl structure) is 5.14 amstrong . Assuming anion-anion contact, calculate the ionic radius for chloride ion.

How to assume anion-anion contact ? Can anyone help with a 3D figure?
 
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The NaCl structure is very easily found via an Internet search. Do you know which atom is the anion (i.e., how an anion is defined)?
 
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