What is meant when someone says 50% solution of NaCl?

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When discussing solutions like a 50% NaCl or a 35% ethylene glycol solution, it's crucial to clarify whether the percentage refers to weight/volume (w/v) or volume/volume (v/v). A 50% (w/v) NaCl solution indicates 50 grams of NaCl dissolved in 100 mL of water. In contrast, a 35% ethylene glycol solution typically means 35 mL of ethylene glycol combined with 65 mL of water, totaling 100 mL of solution. While it's noted that volumes do not always add up perfectly, for practical laboratory purposes, minor discrepancies are generally acceptable. The interpretation often leans towards understanding the percentage as the amount of solute in relation to the total solution.
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when someone talks about a 50% NaCl solution or a 35% ethylene glycol solution, what does this really mean? Is this the percentage of the solute in the solution by mass, moles, or what?
Thanks.
 
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mikepl1 said:
when someone talks about a 50% NaCl solution or a 35% ethylene glycol solution, what does this really mean? Is this the percentage of the solute in the solution by mass, moles, or what?
Thanks.

Depends if you see v/v (volume/volume) or w/v (weight/volume) %. 50% (w/v) NaCl would be 50 grams in 100 mL of water. 35% ethylene glycol would be 35 mL ethylene glycol + 65 mL water = 100 mL solution, but 35% of that solution is ethylene glycol.

In reality volumes don't add, but 99% of the time for lab purposes it doesn't matter if you're off by 0.01 mL.
 
gravenewworld said:
Depends if you see v/v (volume/volume) or w/v (weight/volume) %. 50% (w/v) NaCl would be 50 grams in 100 mL of water.
I always interpreted that to be 50 grams of NaCl in 100 mL of solution (solution = water + salt).
 
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