Finding the work function using stop potential

AI Thread Summary
The discussion centers on calculating the work function from a photoelectric effect experiment, where a stopping potential of 1.93V is measured with 200nm light. The user initially uses incorrect units for Planck's constant, leading to an erroneous calculation of the work function, Eo. Participants clarify that while the Planck's constant used is in eV-s, it should not be combined with the electron charge in the equation. The correct approach involves either dropping the electron charge or converting all quantities to consistent units. Ultimately, the recalculated work function aligns with known values for materials like potassium or sodium.
Calmeir
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Apologies, but I have another photoelectron question. In this one I get a result that seems reasonable, however it does not show up on my list of work functions that I have available to choose from. The problem is:

A photoelectric-effect experiment finds a stopping potential of 1.93V when light of 200nm is used to illuminate the cathode. What is the cathode made of?

I initially thought this would be an easy problem as Vstop = (hf - Eo) / e

I have all the values except Eo which is what I am trying to solve for.

Vstop = 1.93 V
h = 4.14x10^-15 eV
f = 3x10^8/200x10^-9 = 1.5x10^15
e = 1.6x10^-19

So, I plug all of the values into the equation and solve for Eo

1.93 = ((4.14x10^-15)(1.5x10^15)-Eo)/1.6x10^-19

The resulting value of Eo was 6.21
This seems valid, except the list I have to choose from is:

Potassium: 2.3
Sodium: 2.75
Aluminum: 4.28
Tungsten: 4.55
Copper: 4.65
Iron: 4.7
Gold: 5.1

Likely I am having the same problem as my previous question and not seeing a simple unit difference. Anyhow, I do appreciate your help.
 
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Calmeir said:
h = 4.14x10^-15 eV

That is not Planck's constant in SI units. In fact h is not expressed in eV in any system of units.
 
Tom Mattson said:
That is not Planck's constant in SI units. In fact h is not expressed in eV in any system of units.

Tom is right and wrong. The problem IS units, but the Planck's constant being used by Calmeir is in eV-s, which is correct. The problem is that he is already working in eV, and so needs to drop the "1.6x10^-19" at the end of his equation.

I reworked it and got e=4.28 eV.

-Dan
 
topsquark said:
Tom is right and wrong.

No, Tom is right and right! :biggrin:

The problem IS units, but the Planck's constant being used by Calmeir is in eV-s, which is correct.

While the numerical value of h that he used corresponds to h in eV-s, he did report the units in eV, which is wrong.

The problem is that he is already working in eV, and so needs to drop the "1.6x10^-19" at the end of his equation.

That's one fix, but I was hinting at a different one. Since he put all of his other quantities in SI units I was trying to get him to put h in SI units as well. He would have obtained E0 in Joules and then convert to eV. Changing h to eV-s and leaving the electron charge as e is certainly more direct though...
 
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