How Is the Number of Molecules Calculated in Maxwell Speed Distribution?

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Homework Help Overview

The discussion revolves around calculating the number of molecules of an ideal gas with speeds between 0 and a specified value v, using the Maxwell speed distribution. The original poster presents a formula involving the error function and seeks clarification on a specific algebraic manipulation related to an integral in their solution attempt.

Discussion Character

  • Exploratory, Mathematical reasoning, Problem interpretation

Approaches and Questions Raised

  • The original poster attempts to understand a manipulation of an integral involving the error function and seeks clarification on how to apply integration by parts. Some participants suggest that integration by parts is the key to resolving the confusion.

Discussion Status

Participants are actively engaging with the original poster's question, with some providing guidance on the method of integration by parts. There is an acknowledgment of the challenge posed by the integral, and the discussion appears to be moving towards a clearer understanding of the algebraic manipulation involved.

Contextual Notes

The original poster expresses uncertainty about the algebraic steps in the textbook solution, indicating a potential gap in understanding the integration technique required. The discussion reflects a collaborative effort to clarify this aspect without reaching a definitive conclusion.

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Homework Statement


Show that the number [tex]N(0,v)[/tex], of molecules of an ideal gas with speeds between 0 and v is given by

[tex]N(0,v) = N \left[ erf(\xi) - \frac{2}{\sqrt{\pi}} \xi e^{-\xi^2} \right][/tex]

Where,

[tex]erf(\xi) = \frac{2}{\sqrt{\pi}} \int_{0}^{\xi} e^{-x^2} dx[/tex]

And,

[tex]\xi^2 = \left(\frac{mv^2}{2kT} \right)[/tex]

Homework Equations



[tex]\frac{dN_v}{N} = \sqrt{\frac{2}{\pi}} \left( \frac{m}{kT}\right)^{\frac{3}{2}} v^2 e^{\frac{-mv^2}{2kT}} \ dv[/tex]

The Attempt at a Solution



Alright, so I managed to get to the following

[tex]\frac{dN_v}{N} = \frac{4}{\sqrt{\pi}} x^2 e^{-x^2} dx[/tex]

Where,

[tex]\alpha = \frac{m}{2kT}, \ x = \sqrt{\alpha}v[/tex]

=========================\\===========================

So far so good, but now when checking the solution on the textbook it claims the following algebraic manipulation which I can't follow

[tex]\frac{2N}{\sqrt{\pi}}\int_{0}^{\xi} x (2xe^{-x^2} dx) = \frac{2N}{\sqrt{\pi}} x e^{-x^2} |_{\xi}^{0} \ + \ N \frac{2}{\sqrt{\pi}} \int_{0}^{\xi} e^{-x^2} dx[/tex]

What was done on the integral above, how can you "split" it like that?
 
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Integration by parts
 


It's integration by parts. udv=d(uv)-vdu with u=x and dv=(2x)e^(-x^2)dx.
 
L-x said:
Integration by parts

But of course! Agh, how didn't I see that, I feel very stupid right now. :biggrin:

Thanks for the highlight, L-x!
 
No worries. It's not immidiately obvious, although the integral is written in a way which gives you a clue: x(2x) instead of 2x^2
 

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