How Can the Equivalent Weight of Sulfur be 32 in S2Cl2?

AI Thread Summary
The discussion centers around the calculation of the equivalent weight of sulfur in the compound S2Cl2, with a focus on the confusion regarding its value. The equivalent weight of sulfur in SCl2 is stated as 16, leading to the question of how it can be 32 in S2Cl2. The formula for equivalent weight is clarified as atomic weight divided by valency, with sulfur having variable valencies of 2, 4, and 6. This results in equivalent weights of 16, 8, and 32/6 for different compounds. The main point of contention is the assertion that sulfur cannot have a valency of 1, which raises questions about the validity of the equivalent weight being 32 in S2Cl2. Additionally, there is a critique of the continued teaching of equivalent weight as a concept, suggesting it may be outdated.
avistein
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Equivalent weight of sulfur in SCl2 is 16,what is the equivalent weight of S in S2Cl2? [S=32,Cl=35.5]

I know that the answer is 32. But how how can the equivalent weight of Sulfur be 32?
We know that equivalent weight=atomic weight/valency
Now sulfur has variable valency of 2,4,6 .So the equivalent weight will be 16,8 and 32/6(as atomic weight of sulfur is 32 ) in different equation.But how can the equivalent weight be 32,when sulfur cannot have a valency of 1? Please exaplain.
 
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avistein said:
Equivalent weight of sulfur in SCl2 is 16,what is the equivalent weight of S in S2Cl2? [S=32,Cl=35.5]

I know that the answer is 32. But how how can the equivalent weight of Sulfur be 32?
We know that equivalent weight=atomic weight/valency
Now sulfur has variable valency of 2,4,6 .So the equivalent weight will be 16,8 and 32/6(as atomic weight of sulfur is 32 ) in different equation.But how can the equivalent weight be 32,when sulfur cannot have a valency of 1? Please exaplain.

Who still teaches such outdated concepts as equivalent weight?
 
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