Mentz114 said:
In a thermodynamic ensemble, counting microstates is a valid procedure, but it's not meaningful in single quantum events like when a photon encounters a beam splitter.
Unfortunately we don't have a
single quantum event of a photon encountering a beam splitter. We have a single photon encountering a beam splitter and causing a lot of entropy in the environment (via the interactions with the photomultipliers, heater, etc).
The whole point of this thought experiment is to illustrate
how the probabilities on the outcome of a single quantum event can be influenced by the future entropy considerations.
The fact that they
are influenced is trivial. Simply consider the setup with the quantum harmonic oscillators from my message "Oct21-09 08:10 PM".
Mentz114 said:
The overlap between QM and thermodynamics seems to be important only when there's entanglement. See
http://arxiv.org/abs/0905.2562
Correct me if I wrong, but it sounds like that you are thinking that the entanglement is a small and unimportant factor. Some "spooky action at the distance". That disappear almost instantly in any noticeable environment temperature. Yes. Clean "EPR-paradox" entanglement in fact disappears very fast. But only because of the other
entanglements with the environment. Decoherence is entanglement with the environment. See a Wikipedia article on the decoherence, or any other generic introduction on the subject i.e.:
http://arxiv.org/abs/quant-ph/9803052. Theoretically the entangled states can stay at
any temperatures at
any distance for an
unlimited period of time. This is trivial from the unitarity principle in the QM. There have been experiments (reported in the Nature/Nature Physics, I can locate you the articles), directly confirming that the entangled states can stay at large distances (miles) over the large periods of time.
So yes. I would very much agree that "the overlap between QM and thermodynamics seems to be important only when there's entanglement". Only I would say that the entanglement is
very very important. And if the Second Law is simply the effect caused by the Decoherence with the time flow, the entanglement would be the
only important factor in the thermodynamics.
-- Dmtr