About mixed integral for perturbation in hydrogen atom

In summary, the conversation discusses the transformation of an integral from cartesian to polar coordinates in the calculation of hydrogen atom perturbation. The participants also mention the use of symmetry to simplify the integral.
  • #1
ntusg
8
0

Homework Statement



During my calculation of hydrogen atom perturbation, I need to integral below in cartesian coordinate. It is given that below integral can be transformed.

Homework Equations



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Anyone could help to see what will the transformed integral in polar coordinate if the left-hand-side integral were changed to r*x^2*exp(-r) instead of x^2*exp(-r).

Thanks.

The Attempt at a Solution

 
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  • #2
They are just using that the integral of x^2*exp(-r), y^2*exp(-r) and z^2*exp(-r) are all equal by symmetry. So if you add them all together you get r^2*exp(-r). Hence the '1/3'. Putting another r in front of x^2*exp(-r) doesn't stop you from doing the same thing.
 
  • #3
Hi Dick, I just got it, and it only about rewriting dV in Cartesian to the polar coordinate.
Thanks for the help!
 

FAQ: About mixed integral for perturbation in hydrogen atom

1. What is a mixed integral for perturbation in hydrogen atom?

A mixed integral for perturbation in hydrogen atom is a mathematical expression used to calculate the energy levels and wave functions of an atom that has been perturbed, or disturbed, by an external force or interaction. It takes into account the combined effects of both the unperturbed and perturbed Hamiltonians on the atom's energy levels and wave functions.

2. How is a mixed integral for perturbation in hydrogen atom different from a regular integral?

A mixed integral for perturbation in hydrogen atom is different from a regular integral in that it involves integrating over both time and space, rather than just space. This is because perturbation in the hydrogen atom occurs over time, and the perturbed wave function is a function of both time and space.

3. What is the importance of mixed integrals for perturbation in hydrogen atom?

Mixed integrals for perturbation in hydrogen atom are important because they allow us to accurately calculate the energy levels and wave functions of perturbed atoms, which is crucial in understanding and predicting the behavior of atoms in various environments. They also provide insight into the effects of external forces and interactions on the atom's properties.

4. How are mixed integrals for perturbation in hydrogen atom calculated?

Mixed integrals for perturbation in hydrogen atom are calculated using mathematical techniques such as perturbation theory and variational methods. These methods involve breaking down the perturbed Hamiltonian into a series of simpler Hamiltonians, which can then be integrated over time and space to obtain the mixed integral.

5. Are there any real-world applications of mixed integrals for perturbation in hydrogen atom?

Yes, mixed integrals for perturbation in hydrogen atom have numerous real-world applications, particularly in the field of quantum mechanics. They are used in the study of atomic and molecular systems, as well as in the development of new technologies such as quantum computing. They are also essential in understanding and predicting the behavior of atoms in various physical and chemical environments.

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