A
skeleton for a category is a full subcategory with the properties that:
(1) Any two isomorphic objects in the skeleton are equal
(2) Any object of the category is isomorphic to an object of the skeleton
A category is
small iff it has a set of objects and a set of morphisms.
A category is
skeletally small if it has a small skeleton.
Intuitively, a skeleton is what you get when you replace everything with its isomorphism class, so being skeletally small means that there is a set of isomorphism classes.
From a technical standpoint, when basing everything on ZFC, the trick to implementing this idea is to find a canonical representative for each isomorphism class (because each isomorphism class is a proper class, so you don't have much freedom in manipulating them), and then showing there is a set of representatives.
Actually, this is far easier if you're allowed to assume a large cardinal.

Then, you have a (large) set of all
small algebraic extensions of your base field.
Another way to make this easier is to assume a strong form of the axiom of choice that applies to proper classes as well as sets.