Balancing using half reaction method

In summary, the redox reaction given involves the conversion of H2CO to HCOOH and Ag+ to Ag in basic solution. The oxidation numbers have been determined, and it has been found that Ag is reduced while H2CO is oxidized. However, the half reactions cannot be balanced and the attempt to do so resulted in an unbalanced equation involving OH-. The final equation suggested has a coefficient of 2 for OH-, but the charge, carbon, oxygen, and hydrogen are still not balanced and require further checking.
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Homework Statement



The redox reaction below occurs in basic solution. Balance it with the smallest whole number coefficients and determine the coefficient for OH-.

H2CO(g) + Ag+(aq) ---> HCOOH(aq) + Ag(s).



Homework Equations



The Attempt at a Solution



I got the oxidation numbers and found that Ag is reduced and the H2CO is oxidized, but I can't balance the half reactions, this is what I came up with:

Ag+ + 1e- ---> Ag

H2CO + H2O ---> 2HCOOH + 1e- + H2O
Any help?
 
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  • #2
sorri i think i got it, can someone check?:

2OH- + H2CO ---> 2HCOOH + 1e- + H2O

so the coefficient for OH- is 2?
 
  • #3
Charge is not balanced, carbon is not balanced, oxygen is not balanced... haven't checked hydrogen.
 

What is the half reaction method and why is it used in balancing chemical equations?

The half reaction method is a technique used to balance redox reactions, where electrons are transferred between reactants and products. This method breaks the reaction into two half reactions: the oxidation half reaction, where electrons are lost, and the reduction half reaction, where electrons are gained. By balancing each half reaction separately, the overall equation can be balanced. This method is used because it allows for a more systematic and accurate approach to balancing redox reactions.

What are the steps involved in balancing a chemical equation using the half reaction method?

The first step is to write out the unbalanced equation and identify the species being oxidized and reduced. Then, write the half reactions for each species, making sure to balance the number of atoms and charges on each side. Next, balance the number of electrons in each half reaction by adding or subtracting electrons. The next step is to multiply each half reaction by the necessary coefficient to make the number of electrons equal in both reactions. Finally, add the two half reactions together, cancelling out any common terms, to get the balanced overall equation.

Can the half reaction method be used to balance non-redox reactions?

No, the half reaction method is specifically designed for balancing redox reactions, where there is a transfer of electrons between reactants and products. For non-redox reactions, other methods such as the inspection method or algebraic method may be used.

What are some common mistakes to avoid when using the half reaction method?

One common mistake is forgetting to balance the number of atoms and charges in each half reaction before balancing the electrons. Another mistake is not multiplying the half reactions by the necessary coefficient to make the number of electrons equal before adding them together. It is also important to double check the final balanced equation to ensure all terms are properly cancelled out.

Are there any shortcuts or tips for balancing redox reactions using the half reaction method?

One tip is to start by balancing elements that are not involved in the redox reaction, such as oxygen or hydrogen, and then move on to balancing the electrons and charges. Another tip is to use the smallest possible coefficients to balance the electrons and avoid using fractions. Additionally, it can be helpful to double check the final balanced equation by counting the number of atoms on each side to ensure they are equal.

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