Bose-Einstein-Condensate ground state energy E_0 = 0

Derivator
Messages
147
Reaction score
0
Hi,

why is the ground state energy usually set to E_0 = 0 for a Bose gas?

Normally one looks at a particle in a box, where the ground state energy should be different from 0.

Here is the "particle in a box ground state energy" calculated in a Bose-Einstein contex:
http://books.google.com/books?id=rI...A#v=onepage&q=bose gas "zero energy"&f=false"
The author finds E_0 = 0

In the follwoing calculation however, we find, as usual, that the ground state energy is not 0:
http://en.wikipedia.org/wiki/Particles_in_a_box#Energy_levels"

How come, we can choose the ground state energy =0 for the Bose-Einstein-Condensate problem?


--
derivator
 
Last edited by a moderator:
Physics news on Phys.org
First off all, it's just a constant shift of the energy spectrum -- it's quite common to shift the Hamiltonian such that the lowest energy state has zero energy.

But, the links you are providing do not treat the same problem: the first link has periodic boundary conditions, the wiki article does not. So a wavefunction which is constant everywhere appears in the first problem, but not in the second. A wavefunction which is constant, has zero derivatives and therefore zero kinetic energy.
 
Insights auto threads is broken atm, so I'm manually creating these for new Insight articles. Towards the end of the first lecture for the Qiskit Global Summer School 2025, Foundations of Quantum Mechanics, Olivia Lanes (Global Lead, Content and Education IBM) stated... Source: https://www.physicsforums.com/insights/quantum-entanglement-is-a-kinematic-fact-not-a-dynamical-effect/ by @RUTA
If we release an electron around a positively charged sphere, the initial state of electron is a linear combination of Hydrogen-like states. According to quantum mechanics, evolution of time would not change this initial state because the potential is time independent. However, classically we expect the electron to collide with the sphere. So, it seems that the quantum and classics predict different behaviours!
Back
Top