Can Ammonium Bicarbonate 'salt out' ethanol alcohol?

AI Thread Summary
Ammonium Bicarbonate is being tested for its potential to 'salt out' ethanol in fermentation processes. The discussion raises questions about whether Ammonium Bicarbonate can effectively separate alcohol from water, similar to other ionic compounds like Sodium Carbonate and Ammonium Sulfate. It is noted that Ammonium Bicarbonate decomposes in water, producing ammonia gas, carbon dioxide, and water. This decomposition process may influence its ability to separate ethanol from water, as gas-forming reactions typically favor a positive entropy change. The inquiry focuses on the compound's behavior in alcoholic solutions and its effectiveness in the salting-out process.
ejnovek
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I'm testing Ammonium Bicarbonate in a fermentation process. Is it possible for Ammonium Bicarbonate to 'salt out' Ethanol? Compounds such as Sodium Carbonate and Ammonium Sulfate are able to salt out ethanol.
 
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Sounds like a good measurement project.
 
Does the Ammonium Bicarbonate decompose in the alcohol or is it able go separate the alcohol from the water? As an ionic compound, is it able to 'salt out' alcohol like other ionic compounds?
 
ejnovek said:
Does the Ammonium Bicarbonate decompose in the alcohol or is it able go separate the alcohol from the water? As an ionic compound, is it able to 'salt out' alcohol like other ionic compounds?

Ammonium Bicarbonate = [NH4+][HCO3-]. This will decompose in H2O, I believe... [NH4+] + [HCO3-] --> NH3 (g) + CO2 (g) + H2O (l) [Gas forming reactions tend to go becasue of the large positive entropy change when producing a gas...]
 
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