Sorry for delayed response. Server problems.
chemisttree said:
Not a big deal.
You received the partially correct answer. It's actually due to both resonance and inductive effects. You reasoned out how the formal charge produced the resonance effect and asked, "Right? Is this the reason for my question?" Hmmmm. How was the poster to answer that?
By answering "yes" or "no".
So it was partially correct, not fully ?*
If you had asked how to look for an answer using GOOGLE, I would have been right there with an answer.
Alright. I know how to google. You do not have to teach me that.
Search terms? I used terms which you had in your question and I found the answer easily. First page.
I apologize. I did the same thing but could not find the answer. Can you give me a link which contains the answer ? Thanks.
Sorry, but when you misrepresent yourself (many questions unanswered nonsense) and bash our forum, expect equal treatment.
I did not bash any forum.
You brought the question I asked online, in this context. I never even mentioned it. It were
you who became hyper by seeing that "too many" phrase.
Fine then, if you say so.
www.Sciencemadness.com is a dead link but I know it once worked. And negative mesomeric effect doesn't affect the inductive effect. The inductive effect is due to the three bonds nitrogen shares with the very electronegative oxygens. Inductive is not resonance and resonance is not inductive.
Sorry, it is
www.Sciencemadness.org. Yes, I know inductive effect, a permanent effect is due to slight displacement of sigma electrons, whereas mesomeric effect is due to displacement(oscillation) of pi electrons. Latter occurs when an electronegative atom, atom with lone pair, or charged atom is in conjugation with pi bond. Former and latter do have some similarities also. Again, in NO
2 there is one pi bond between nitrogen and oxygen, one coordinate bond between nitrogen and oxygen and a lone pair on nitrogen, and not "three" sigma bonds.
ChiralWaltz said:
1) I would have called it "NO2 and Inductive Effects". I'm trying to help you get your question noticed.
Fine.
2) I didn't know. May I please see the rule you are speaking of?
It states that one should clearly state the question to be discussed. What I did is not against the rules.
3) I'm not sure. Please tell me what error I made in trying to understand your question.
You did not mention the "type" of inductive effect.