Can Solids Really Burn Underwater?

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Cooking oats in water can lead to scorching due to thermal decomposition, which occurs even without oxygen. While water typically prevents combustion by smothering flames, the heat can still decompose organic materials, resulting in a burnt smell and charred appearance. This process, known as charring, happens before any combustion reaction can take place. Certain substances, like magnesium, can burn underwater because they can extract oxygen from water molecules, but this is not applicable to oats. Understanding the distinction between thermal decomposition and combustion clarifies why oats can scorch despite being submerged in water.
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I was cooking oats in water yesterday and the oats at the bottom of the pot got scorched. How is this possible? Doesn't the water smother the oats from oxygen?
 
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You don't need oxygen for the thermal decomposition of the organic substances.

In other words: nothing was burnt.
 
But doesn't a combustion reaction proceed?
 
UMath1 said:
But doesn't a combustion reaction proceed?

No.
 
Alright. So thermal decomposition can produce the same burnt smell and charred look that burning can?
 
Yes. Charring is part of the burning - heat decomposes organic matter even before it starts to react with the oxygen.
 
Thanks!
 
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There are some substances that can actually "burn" under water because they are more powerful reducing agents than hydrogen and can therefore take the bound oxygen from water molecules. Magnesium metal is one example of this.
 
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