Change in Enthelpy with no Heat Exchange?

AI Thread Summary
A change in entropy can occur in a cycle without net heat exchange, particularly in non-quasistatic and adiabatic processes. While a complete cycle returns a system to its original state, the entropy can still change due to irreversible processes. The principle of maximum entropy suggests that a system evolves towards equilibrium, but this can happen in adiabatic conditions without constant internal energy. To calculate the change in entropy, one can use the formula ΔS = ∫dQrev/T, determining the reversible path between the initial and final states. Understanding these concepts is crucial for thermodynamics studies.
Zenderson3
Messages
2
Reaction score
0
This is a rather general question but I'm studying for my thermodynamics final and wanted to clarify this topic.

Is it possible for there to be a change in entropy in a cycle without a net exchange of heat into or out of the system? If so what may be some of the examples of this and how would (if you can) would you calculate this change.

I know the principle of maximum entropy describes that a system would evolve to the equilibrium point of maximum entropy but would it do this if it were adiabatic or does the change in internal energy need to remain constant?

Also I know that if a process is non-quasistatic and adiabatic the entropy will change but is there anyway to calculate this value?
 
Science news on Phys.org
Zenderson3 said:
This is a rather general question but I'm studying for my thermodynamics final and wanted to clarify this topic.

Is it possible for there to be a change in entropy in a cycle without a net exchange of heat into or out of the system? If so what may be some of the examples of this and how would (if you can) would you calculate this change.
In one complete cycle, a system returns to its original state. So its entropy must be the same. (did you mean enthalpy or entropy in your title?)

I know the principle of maximum entropy describes that a system would evolve to the equilibrium point of maximum entropy but would it do this if it were adiabatic or does the change in internal energy need to remain constant?
No sure what you are getting at. Can you give an example?

Also I know that if a process is non-quasistatic and adiabatic the entropy will change but is there anyway to calculate this value?
Sure. ΔS = ∫dQrev/T

You just need to determine the reversible path between the beginning and end states and calculate the integral along that path.

AM
 
I need to calculate the amount of water condensed from a DX cooling coil per hour given the size of the expansion coil (the total condensing surface area), the incoming air temperature, the amount of air flow from the fan, the BTU capacity of the compressor and the incoming air humidity. There are lots of condenser calculators around but they all need the air flow and incoming and outgoing humidity and then give a total volume of condensed water but I need more than that. The size of the...
Thread 'Why work is PdV and not (P+dP)dV in an isothermal process?'
Let's say we have a cylinder of volume V1 with a frictionless movable piston and some gas trapped inside with pressure P1 and temperature T1. On top of the piston lay some small pebbles that add weight and essentially create the pressure P1. Also the system is inside a reservoir of water that keeps its temperature constant at T1. The system is in equilibrium at V1, P1, T1. Now let's say i put another very small pebble on top of the piston (0,00001kg) and after some seconds the system...
I was watching a Khan Academy video on entropy called: Reconciling thermodynamic and state definitions of entropy. So in the video it says: Let's say I have a container. And in that container, I have gas particles and they're bouncing around like gas particles tend to do, creating some pressure on the container of a certain volume. And let's say I have n particles. Now, each of these particles could be in x different states. Now, if each of them can be in x different states, how many total...
Back
Top