Classical thermodynamics problem

In summary, the Second Law of Thermodynamics can be stated in two forms: Kelvin's statement and Clausius' statement. For a particular solid at low temperatures, the heat capacity per unit volume is equal to CT3. To find the expressions for its internal energy and entropy S per unit volume, we can use the formula Heat capacity = Internal energy/ Temperature, giving us an internal energy of CT4. However, this is incorrect and the purpose of seeking help on the forum is to quickly solve the problem and avoid spending a long time on it.
  • #1
spaghetti3451
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Homework Statement



(i) State the Second Law of Thermodynamics in one or other of its forms.

(ii) The heat capacity per unit volume of a particular solid at low temperatures is equal to CT3; find expressions for its internal energy and entropy S per unit volume (ignoring the effects of thermal expansion).

Homework Equations



The Attempt at a Solution



(i) Kelvin's statement: No process is possible whose sole effect is complete conversion of heat into work.

Clausius' statement: No process is possible whose sole effect is to transfer heat from a colder to a hotter body.

(ii) Not sure. Any help would be awesome.
 
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  • #2
Atleast show us the attempt
 
  • #3
Heat capacity = Internal energy/ Temperature, so Internal energy = CT4. Now, I know that this is wrong, but that's the point of me coming to the forum, so I can get the problem done quickly. Otherwise I can just read the lecture notes and get the problem done in 60 long and boring minutes, which isn't fun becasue I am a third year student and I am studying this for the comprehensive paper and if I take this long to do one problem, then i will take eternity to finish all the first and second year courses and so I might as well pack my bag and run for home.
 

1. What is classical thermodynamics?

Classical thermodynamics is a branch of science that deals with the study of energy and its transformations, particularly in relation to the physical properties of matter. It is a fundamental part of physics and chemistry that helps us understand how energy is transferred and utilized in different systems.

2. What is the first law of thermodynamics?

The first law of thermodynamics, also known as the law of conservation of energy, states that energy cannot be created or destroyed, only transferred or converted from one form to another. This means that the total energy in a closed system remains constant.

3. What is the difference between heat and temperature in classical thermodynamics?

Heat is the transfer of thermal energy between two objects due to a difference in temperature, while temperature is a measure of the average kinetic energy of the particles in a substance. In classical thermodynamics, heat is considered a form of energy, while temperature is a measure of the intensity of that energy.

4. What is the second law of thermodynamics?

The second law of thermodynamics states that in any energy transfer or conversion, some energy will be lost in the form of heat. This is because no process can be 100% efficient, and some energy will inevitably be wasted. It also states that the total entropy of a closed system will always increase over time.

5. How is classical thermodynamics applied in everyday life?

Classical thermodynamics has many practical applications in our daily lives, such as in the design and operation of engines, refrigerators, and air conditioners. It also helps us understand the behavior of gases, liquids, and solids, and how heat transfer affects our surroundings. Additionally, it plays a crucial role in the production and utilization of energy in various industries.

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