Confused on phase diagrams for binary systems (thermodynamics)

AI Thread Summary
In binary liquid systems, raising the temperature at constant pressure can lead to partial vaporization, allowing some liquid to remain until the mixture is fully vaporized. Unlike pure substances, which have a specific temperature for phase transitions, mixtures do not have a single transition temperature, confirming that multiple temperatures can exist for varying vaporization levels. The concept of latent heat is not meaningless for mixtures; it can be calculated through enthalpy balances in flow systems to determine the heat required for vaporization. The phase rule can help explain the relationship between temperature, pressure, and the amount of vaporized liquid. Understanding these dynamics is crucial for accurately analyzing phase behavior in binary systems.
fluidistic
Gold Member
Messages
3,928
Reaction score
272
I'm confused regarding the phase diagrams of binary systems. Let's suppose we mix 2 liquids, A and B at a given pressure P that won't change during the whole experiment. I raise the temperature until I observe that some of the mix of liquids vaporizes. What boggles me is that it seems I can actually raise the temperature and there's still liquid remaining (less and less if I raise the temperature more and more), until when I raise the temperature enough and it vaporizes entirely.
But as far I as thought previously, you could not raise the temperature without the liquid passing entirely to gas if you saw it started to vaporize.
I mean, for a pure substance it seems that at a given pressure there's a single temperature at which there's a phase transition.
Now for a mix of substance, there is no more a single temperature for which there's a phase transition. Is this correct?
If it's correct, is the latent heat meaningless for mix of substances?
 
Science news on Phys.org
Yes. For a solution of two components, if you hold the pressure constant, the temperature will still change depending on how much is vaporized. You can verify this by applying the phase rule. I'm not sure if the term latent heat is totally meaningless. If you carry out a flash calculation for a flow system at constant pressure, and specify the fraction of the original liquid that vaporizes, you can precisely determine the amount of heat required by doing an enthalpy balance.
 
I was watching a Khan Academy video on entropy called: Reconciling thermodynamic and state definitions of entropy. So in the video it says: Let's say I have a container. And in that container, I have gas particles and they're bouncing around like gas particles tend to do, creating some pressure on the container of a certain volume. And let's say I have n particles. Now, each of these particles could be in x different states. Now, if each of them can be in x different states, how many total...
Thread 'Why work is PdV and not (P+dP)dV in an isothermal process?'
Let's say we have a cylinder of volume V1 with a frictionless movable piston and some gas trapped inside with pressure P1 and temperature T1. On top of the piston lay some small pebbles that add weight and essentially create the pressure P1. Also the system is inside a reservoir of water that keeps its temperature constant at T1. The system is in equilibrium at V1, P1, T1. Now let's say i put another very small pebble on top of the piston (0,00001kg) and after some seconds the system...
Back
Top