The discussion centers on the distinction between combustible substances and supporters of combustion. A combustible substance is defined as a material that burns, while a supporter of combustion, such as oxygen (O2), is an oxidizer that facilitates the burning process. The conversation highlights the importance of understanding these concepts in chemistry, with one participant expressing frustration over the lack of clarity in textbooks. Additionally, a thought experiment is proposed involving a room filled with methane and a Bunsen burner using only compressed air, suggesting a unique approach to exploring combustion dynamics, though it is advised not to attempt this in reality.