Constants like Avogadro's Number, Planck's Constant, and the Gravitational Constant have dimensions due to their roles in equations, while pure numbers like 1, 2, and 3 are dimensionless. The Gravitational Constant, G, has units of 1/(kg sec^2) to balance the units in the equation F = -GmM/r^2. Avogadro's Number is dimensionless as it represents the number of molecules per mole, while Planck's Constant has units of kg m^2/sec to maintain energy unit consistency in the equation E = hν. The discussion also highlights that constants can be dimensionless in certain contexts, such as the speed of light in relativity, which is treated as dimensionless. Understanding units as constants helps clarify their compatibility in mathematical expressions.