High School Does a hot coffee have bigger mass than a cold coffee?

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The discussion centers on the concept of mass in relation to temperature, specifically whether hot coffee has a greater mass than cold coffee. It clarifies that while the invariant mass of a system is independent of speed, the kinetic energy of particles in a hot cup of coffee contributes to its overall invariant mass, making it effectively "heavier" than cold coffee. However, this increase in mass is negligible compared to other factors like thermal expansion, which results in lower density for hot coffee. The conversation also touches on the non-additive nature of mass in composite systems and the distinction between rest mass and the effects of kinetic energy. Ultimately, the complexities of mass and energy in thermodynamic systems are highlighted, emphasizing that real-world measurements can complicate theoretical discussions.
  • #61
vanhees71 said:
The mass is given by the entire internal energy of the composite system, not only the sum of the kinetic energies + rest energies of their constituents
Therefore, if there is a potential describing the interaction between system's constituents, we can just include in the system's total internal energy also the total potential energy without the need to introduce force field with its 4-momentum.
 
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  • #62
There is no potential describing the interaction between the system's constituents. There's a famous no-go theorem that any attempt to create such a theory (at least if you assume that it can be formulated in terms of the action principle) of interacting point particles you fail. The really successful relativistic theories are all field theories. On the classical level matter should be described by continuum rather than point-particle mechanics to get a fully consistent theory.

There was a lot of progress in the recent years concerning relativistic hydrodynamics, derived via relativistic kinetic theory from quantum field theory.
 
  • #63
Mister T said:
I don't know how to define inertial mass in special relativity, but resistance to acceleration gives a weird result. The resistance to acceleration gives different results depending on the direction of the force.
You don’t really. Inertial mass is a concept of classical mechanics. In relativity ”mass” generally refers to rest energy. To me, the real beauty of ##E = mc^2## is that the rest energy is equal (with c=1) to a system’s rest frame inertia. Thereby justifying the use of the word “mass” for the rest energy.
 
  • #64
My point was to emphasize that if you try to make sense of point-particle mechanics (which is not so easy, if not impossible, by the way) the quantity mass in (special) relativity is the same as in Newtonian physics, if you use the right description in terms of a manifestly covariant way. The key is to introduce the concept of proper time and Minkoski force.

Of course, point-particle mechanics in relativity is a bit limited, because what you can really describe to some extent is the motion of a free particle and a particle in an external field, neglecting the inevitable interaction with its own field, i.e., in electrodynamics, the electromagnetic Coulomb field around the point particle + the radiation field when it's accelerated and the back reaction of the latter to the particle, aka radiation damping.

If you include the latter inevitable consequences of relativity in point-particle mechanics, you come to the conclusion that you get not much further than to the Landau-Lifshitz approximation of the Lorentz-Abraham-Dirac equation.

A consistent description of interacting point particles is even less convincing. There you don't get further than some corrections to the Newtonian limit.
 
  • #65
vanhees71 said:
There is no potential describing the interaction between the system's constituents
I was thinking, for example, of a gas of bi-atomic molecules. There should be a potential/potential energy for each of them.
 
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  • #66
vanhees71 said:
It doesn't. As soon as you describe everything in a manifestly covariant way, it gets as simp
$$m \frac{\mathrm{d}^2 x^{\mu}}{\mathrm{d} \tau^2}=K^{\mu}(x,\mathrm{d}_{\tau} x,\tau).$$By construction, the "Minkowski force" has to fulfill$$\frac{\mathrm{d} x^{\mu}}{\mathrm{d} \tau} K_{\mu}=0,$$
This is only valid for a pure force, that means a mass-preserving force. A counter-example exists during an elastic collision of objects. The more general definition of force is:
$$\mathbf F=\frac{d}{d \tau} \mathbf P=\frac{d}{d \tau}(m \mathbf U)=m \mathbf A+\frac{dm}{d \tau}\mathbf U$$
Source, see equation (70):
http://www.scholarpedia.org/article/Special_relativity:_mechanics#Four-force_and_three-force
 
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  • #67
Orodruin said:
Time to brew another cup!
We can also put a heating pad under the cup to make the cold coffee warm again. This required a special cup.

The heating pad impresses on the coffee a heatlike 4-force ##\mathbf F =\frac{d}{d \tau}(m \mathbf U)##. In the common rest-frame of coffee and heating pad, it has only a temporal component.

Source:​
Rindler's book "Introduction to Special Relativity", 2nd edition, chapter 35 "Three-force and four-force"​
Short version online:​

The above used definition of 4-force extends Newton's 2nd law to 4 dimensions.

Newton said:
DEFINITION II.​
The quantity of motion is the measure of the same, arising from the velocity and quantity of matter conjunctly.
...
https://en.wikisource.org/wiki/The_Mathematical_Principles_of_Natural_Philosophy_(1846)/Definitions

Newton said:
LAW II.​
The alteration of motion is ever proportional to the motive force impressed; and is made in the direction of the right line in which that force is impressed.
...
https://en.wikisource.org/wiki/The_...l_Philosophy_(1846)/Axioms,_or_Laws_of_Motion
 
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  • #68
Sagittarius A-Star said:
We can also put a heating pad under the cup to make the cold coffee warm again.
Eeeeew.
(While safe, it makes coffee taste more bitter.)
 
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  • #69
Sagittarius A-Star said:
This is only valid for a pure force, that means a mass-preserving force. A counter-example exists during an elastic collision of objects. The more general definition of force is:
$$\mathbf F=\frac{d}{d \tau} \mathbf P=\frac{d}{d \tau}(m \mathbf U)=m \mathbf A+\frac{dm}{d \tau}\mathbf U$$
Source, see equation (70):
http://www.scholarpedia.org/article/Special_relativity:_mechanics#Four-force_and_three-force
I was talking about the formulation of a point-particle theory in special relativity. I've never heard the expression "pure force". What do you mean by that? As I tried to explain the most clear formulation of relativistic point-particle mechanics (which is of way less applicability than in Newtonian physics by the way) is in terms of the manifestly covariant equation with the Minkowski four-force.
 
  • #70
vanhees71 said:
I've never heard the expression "pure force". What do you mean by that?

This expression is used in Rindler's book "Introduction to Special Relativity", 2nd edition, chapter 35 "Three-force and four-force". It means a mass-preserving force and therefore ##\mathbf U \cdot \mathbf F = 0##.

In Wikipedia, they write a disclaimer before defining a pure force:
Wikipedia said:
For a particle of constant invariant mass ##m>0## ...
##{\mathbf {F} =m\mathbf {A} =\left(\gamma {\mathbf {f} \cdot \mathbf {u} \over c},\gamma {\mathbf {f} }\right).}##
Source:
https://en.wikipedia.org/wiki/Four-force#In_special_relativity

The temporal component gets zero in the rest-frame of the particle.
 
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  • #71
Orodruin said:
You don’t really. Inertial mass is a concept of classical mechanics.
I agree. Inertia is not a well-defined quantity in SR.
Orodruin said:
In relativity ”mass” generally refers to rest energy. To me, the real beauty of ##E = mc^2## is that the rest energy is equal (with c=1) to a system’s rest frame inertia. Thereby justifying the use of the word “mass” for the rest energy.
Yes, but why are you using the term "inertia" when speaking about relativistic concepts?
 
  • #72
Orodruin said:
Inertial mass is a concept of classical mechanics.
Mister T said:
I agree. Inertia is not a well-defined quantity in SR.
Orodruin said:
In relativity ”mass” generally refers to rest energy. To me, the real beauty of
is that the rest energy is equal (with c=1) to a system’s rest frame inertia. Thereby justifying the use of the word “mass” for the rest energy.
Mister T said:
Yes, but why are you using the term "inertia" when speaking about relativistic concepts?
Well, Landau and Lifshitz in The Classical Theory of Fields (3rd ed.) clearly embrace the notion of "inertial mass" in the context of general relativity. From chap. 11 "The Gravitational Field Equations", §101 "The Energy-Momentum Pseudotensor", pg. 309:
L and L Quote.jpg
 
  • #73
Mister T said:
I agree. Inertia is not a well-defined quantity in SR.
It is a perfectly well defined concept. It is just not invariant, nor a scalar.

Mister T said:
Yes, but why are you using the term "inertia" when speaking about relativistic concepts?
I … wasn’t. I was answering OP with regards to the classical concept of Newton’s second law. Later I was discussing that the rest energy in relativity turns out to be the same as the inertial mass in the rest frame. In an object’s rest frame, classical mechanics works well for that object. The inertia concept I mentioned above degenerates to scalar multiplication.
 
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  • #74
Therefore the inertial mass from Landau and Lifshitz is the invariant/rest mass.
 
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  • #75
Mister T said:
I agree. Inertia is not a well-defined quantity in SR.

Yes, but why are you using the term "inertia" when speaking about relativistic concepts?
In SR the measure of inertia is the energy-momentum-stress tensor, and that's why in the mathematical expression, this gets the "sources" of the "gravitational fields" in GR due to the equivalence principle. The universality of the corresponding coupling constant (modulo factors Newton's gravitational constant, ##G##) is due to the non-Abelian nature of the local gauge symmetry underlying GR.
 
  • #76
cianfa72 said:
I was thinking, for example, of a gas of bi-atomic molecules. There should be a potential/potential energy for each of them.
So as @vanhees71 said in post#62, we should not include the potential energy of each bi-atomic molecule in the calculation of system's total Energy...
 
  • #77
The invariant mass is the total energy of the system in the rest frame of its center of momentum (natural units, ##c=1##, for simplicty). E.g., for a gas it's the total inner energy in the rest frame of the container.
 
  • #78
vanhees71 said:
The invariant mass is the total energy of the system in the rest frame of its center of momentum (natural units, ##c=1##, for simplicty). E.g., for a gas it's the total inner energy in the rest frame of the container.
Yes, but in the of bi-atomic gas case, the total inner energy includes the rest energies of atoms plus their KE evaluated in rest frame of the system's center of momentum (i.e. the rest frame of the container) plus the potential energy of each bi-atomic molecule.
 
  • #79
Of course. It's the total internal energy of the gas, ##U##, in the center-momentum frame.
 
  • #80
vanhees71 said:
Of course. It's the total internal energy of the gas, ##U##, in the center-momentum frame.
Can we therefore continue to use the concept of potential energy also in special relativity ?
 
  • #81
In some circumstances yes. E.g., for a particle in a static electric field you can write down the Lagrangian (in the (3+1) non-covariant formalism with ##\dot{\vec{x}}=\mathrm{d} \vec{x}/\mathrm{d} t##)
$$L=-m \sqrt{1-\dot{\vec{x}}^2} -q \Phi(\vec{x}).$$
This is of course an approximation, where you neglect radiation-reaction effects.
 
  • #82
vanhees71 said:
In some circumstances yes. E.g., for a particle in a static electric field you can write down the Lagrangian
Sorry, I believe this is the case for a particle in an external given/assigned external electric field.
In the above case, indeed, there is not an external field but the potential energy is due to the interaction between atoms in each bi-atomic molecule.
 
  • #83
The interaction cannot be described by a potential. There's no action at a distance in relativistic physics.
 
  • #84
vanhees71 said:
The interaction cannot be described by a potential. There's no action at a distance in relativistic physics.
Therefore the potential energy for each bi-atomic molecule is not defined in relativity.
 
  • #85
cianfa72 said:
Therefore the potential energy for each bi-atomic molecule is not defined in relativity.
"Potential energy" is the wrong term for what I think @vanhees71 was talking about for the bi-atomic molecule. The bi-atomic molecule (and an individual atom, for that matter) has binding energy: the energy it would take to separate its constituents into free particles. That binding energy makes a negative contribution to the molecule's invariant mass. This is just as true in relativity as in non-relativistic physics.
 
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  • #86
PeterDonis said:
The bi-atomic molecule (and an individual atom, for that matter) has binding energy: the energy it would take to separate its constituents into free particles. That binding energy makes a negative contribution to the molecule's invariant mass.
AFAIK, the binding energy for a bi-atomic molecule should be negative. What is the reason ?
 
  • #87
cianfa72 said:
AFAIK, the binding energy for a bi-atomic molecule should be negative. What is the reason ?
Because it is a negative contribution to the invariant mass of the molecule: the invariant mass of the molecule is less than the sum of the invariant masses of its constituent atoms.
 
  • #88
PeterDonis said:
That binding energy makes a negative contribution to the molecule's invariant mass. This is just as true in relativity as in non-relativistic physics.
In a simple "classical" case of 2 bonded charged particles (plus and minus) the binding energy is the work made by external forces (external w.r.t. the system of 2 particles) to bring the charged particles from infinity to the current system configuration. Such work is negative thus the binding energy as well.
 
  • #89
cianfa72 said:
In a simple "classical" case of 2 bonded charged particles (plus and minus) the binding energy is the work made by external forces (external w.r.t. the system of 2 particles) to bring the charged particles from infinity to the current system configuration. Such work is negative thus the binding energy as well.
Yes. And this is perfectly consistent with what I said in post #87.
 
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  • #90
In this simple case we can think of binding energy as distributed/associated to the electric field.
 

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