How Can Copper Alloys Be Purified Electrochemically?

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Electrochemical purification of copper alloys can be achieved through various methods, primarily focusing on creating a redox couple that allows for the oxidation of impurities while preserving the copper. One common technique mentioned is pickling, which involves treating the alloy with a non-oxidizing acid to solubilize the other metals in the alloy, leaving the copper intact. For organic impurities, heating the copper alloy above 500°C followed by acidic treatment is recommended. The discussion emphasizes the importance of selecting appropriate commercial setups and resources for effective electrochemical purification processes.
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Hi all

How to purify copper alloys electrochemically ? please describe all possible commerically feseable ways and also pls specify any commerical set ups /resource that can do the above process
 
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Hello,

I have no knowledge about commercial aspects of electrochemical purification, but I'd say that if you can produce a redox couple on copper, then you can oxidize the other metal and purify it; but the term "pickling" is frequently used for the thing you're asking for, I think.

Pickling is basicly an acidic treatment, but the acid must be of a non-oxidizing one in order not to corrode copper; the other metal(s) in the alloy will eventually be solubilized and leave copper by going into the solution, and copper will remain intact. This may be a good measure.

If the impurities are organic-based, acidic treatment after heating the copper part beyond 500°C will be more helpful.

These are pure-chemical ways to treat an impure copper alloy, but wait for other friends' posts.
 
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