Exothermic reaction of zeolite and water

AI Thread Summary
Zeolites are utilized in the heating industry for applications such as solar thermal collectors and adsorption refrigeration due to their high heat of adsorption and ability to hydrate and dehydrate while maintaining structural stability. The exothermic reaction that occurs when zeolites transition from dehydrated to hydrated form is significant for harvesting waste and solar heat energy. The temperature rise from mixing 100 grams of dry zeolites with 100 ml of water at room temperature depends on the specific type of zeolite and the heat capacity of the mixture, which is generally lower than that of water. The discussion emphasizes that the actual temperature increase is influenced by the standard reaction enthalpy and the heat capacity of the reactants. Additionally, the duration that zeolites remain warm at room temperature is contingent upon insulation and external temperature conditions.
ErikL
Messages
8
Reaction score
0
So, I was reading about zeolites:
https://en.wikipedia.org/wiki/Zeolite

One of the things it is used for, is in the heating industry, namely:
"Zeolites can be used as solar thermal collectors and for adsorption refrigeration. In these applications, their high heat of adsorptionand ability to hydrate and dehydrate while maintaining structural stability is exploited. This hygroscopic property coupled with an inherent exothermic (energy releasing) reaction when transitioning from a dehydrated to a hydrated form make natural zeolites useful in harvesting waste heat and solar heat energy. Zeolites are also used as a molecular sieve in cryosorption style vacuum pumps.[13]"

The question is, how hot does the exothermic reaction get? how long the zeolites stay warm in room temperature?
 
Chemistry news on Phys.org
ErikL said:
The question is, how hot does the exothermic reaction get?

This isn't the right question. Reaction doesn't "get hot". Reaction mixture or reactants get hot. How hot can it get? Depends on the standard reaction enthalpy and the heat capacity of the mixture.

how long the zeolites stay warm in room temperature?

Depends on the insulation and external temperature. With some tricks you can keep them at constant temperature (despite reaction being exothermic) or hot for months (after reaction ended).
 
Ok let me pin point my question - what is the temperature rise I can expect to get out of 100 grams of dry zeolites and 100ml of water at room temperature, mixed together?
 
A lot depends on the particular zeolite, but to get some rough numbers: quick googling shows this table. Heat capacity of the mixture will be well below that of water - say half of 4.2 J/gK.
 
I want to test a humidity sensor with one or more saturated salt solutions. The table salt that I have on hand contains one of two anticaking agents, calcium silicate or sodium aluminosilicate. Will the presence of either of these additives (or iodine for that matter) significantly affect the equilibrium humidity? I searched and all the how-to-do-it guides did not address this question. One research paper I found reported that at 1.5% w/w calcium silicate increased the deliquescent point by...
I'm trying to find a cheap DIY method to etch holes of various shapes through 0.3mm Aluminium sheet using 5-10% Sodium Hydroxide. The idea is to apply a resist to the Aluminium then selectively ablate it off using a diode laser cutter and then dissolve away the Aluminium using Sodium Hydroxide. By cheap I mean resists costing say £20 in small quantities. The Internet has suggested various resists to try including... Enamel paint (only survived seconds in the NaOH!) Acrylic paint (only...
Back
Top