Find the rate constant, given temperature and activation energy.

AI Thread Summary
The discussion centers on calculating the rate constant for a reaction with a known activation energy of 38.0 kJ/mol at two different temperatures. The user attempts to apply the Arrhenius equation but initially miscalculates due to using incorrect units for the gas constant R. After receiving feedback, they realize that R should be in J, not kJ, which leads to the correction of their calculations. The user expresses gratitude for the clarification that helped identify the error. Accurate unit conversion is crucial for solving rate constant problems in chemical kinetics.
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Homework Statement



A reaction is found to have an activation energy of 38.0 kJ/mol. If the rate constant for this reaction is 1.60 × 102 M-1s-1 at 249 K, what is the rate constant at 436 K?

Homework Equations



ln\frac{K_{2}}{K_{1}}=\frac{E_{a}}{R}\left(\frac{1}{T_{1}}-\frac{1}{T_{2}}\right)

The Attempt at a Solution



Given:

R=8.314
T1=249K
T2=436K
Ea=160

ln(K_{2})=\frac{38}{8.314}\left(\frac{1}{249}-\frac{1}{436}\right)+ln(160)

Which equals 161.257 which is incorrect. Any clues where I went wrong would be greatly appreciated. Thanks in advance.

Joe
 
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Ah ha! I should have noticed that being that R has units of J not Kj. Thank you very much Borek.

Joe
 
kJ, not Kj...
 
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