Finding coefficient of thermal expansion

AI Thread Summary
The discussion focuses on calculating the coefficient of thermal expansion (CTE) using potential energy and interatomic separation distance. The potential energy equation provided includes constants A and B, with attempts made to graph V versus r, resulting in unexpected curves. Clarification is given that the CTE is determined by the relationship between changes in length and temperature, specifically through the formula ΔL/(L*ΔT). Additionally, it is noted that the graphing must consider only positive values for r, as negative distances are not physically meaningful. The conversation highlights the complexities of relating potential energy graphs to thermal expansion properties.
Junkwisch
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Homework Statement



"see attachment" "q1"

Homework Equations



V=\frac{-A}{r}+\frac{B}{r^{10}}
A=5*10^-30
B=8*10^-121

V=potential energy r=interatomic separation distance

Coefficient of thermal expansion = \frac{change in L}{L*change in T}

The Attempt at a Solution



I have tried making graphs for V vs r however it give me a very weird curve. Furthermore, how do I find the coefficient of thermal expansion from potential energy vs interatomic separation distance? All I know is that in a V vs r, if the energy well to the right of the absolute zero is larger than that of the left, the CTE is positive and negative for vice versa.

"see graph 1"

I also try to draw this graph on my graphic calculator but it gives me result similar to y= -1/x
 

Attachments

  • q1.png
    q1.png
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  • graph 1.jpg
    graph 1.jpg
    23.7 KB · Views: 571
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In your plot V(r) you also consider x\leq0, which is not correct, because distance r must be r>0. The coefficient of thermal (linear) expansion alpha relates the change in longitude L and the change in temperature T, \frac{\Delta L}{L}=\alpha \Delta T, in units K-1. So now you have an input for the variation of T...

PS. The energy on the 'left' of the absolute zero is like saying the north of the north pole, or the time before the Big Bang... :O
 
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