Finding the shortwavelength limit of the white spectrum

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Homework Help Overview

The original poster attempts to determine the short wavelength limit of the white or bremsstrahlung spectrum derived from Bragg scattering of X-rays produced by a copper anode. The data is presented as counts versus degrees on a 2-theta scale, with trials conducted using 20 KeV and 30 KeV X-rays. The challenge lies in converting the degree measurements to a wavelength scale to find the intersection point on the x-axis.

Discussion Character

  • Exploratory, Assumption checking, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the need to convert the data from degrees to wavelengths, with the original poster expressing uncertainty about the conversion process. Some suggest using the relationship between the angle and wavelength, while others question the reference point for the angle used in calculations.

Discussion Status

The discussion is ongoing, with some participants providing guidance on the conversion method. The original poster acknowledges a potential error in their calculations but does not reach a conclusion about the correct approach.

Contextual Notes

The original poster's data is constrained to counts versus degrees, and there is uncertainty regarding the correct reference for the angle in relation to the crystal surface. The need for accurate conversion to wavelength is emphasized.

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Homework Statement



I am trying to find the short wavelength limit ( and consequently plankcs constant) of the white or bremstrahlung spectrum. The data came from the bragg scattering of x-rays produced from a copper anode scattered of a NaCl crystal. The graph is counts vs degrees. The spectrum is from 11-30º on a 2-theta scale. There were two trials for the white spectrum, one of 20 KeV x-rays and the other of 30 Kev x-rays. The shortwavelength limit is defined as the intersection of the x-axis.

One of the main equations is,

hf\; =\; h\left( \frac{c}{\lambda } \right)\; =\; \mbox{E}\; =\; 20\; KeV

Homework Equations



The problem is that my data is in counts vs degrees, not counts vs wavelength. I need my x-axis to be in wavelength, not the recorded degrees. I am not sure how to convert it.

The Attempt at a Solution



I am a bit clueless on this one. I tried using 2d*sin(theta) = n*lambda to convert the degree axis into a wavelength axis, I knew it would be wrong iand sure enough, I got a Planck's constant of five magnitudes off.
 
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Surely someone must know! Or is it too hard? :(
 
If you have a rotating crystal and plot signal vs. rotation angle, then by knowing theta (incident angle relative to the crystal surface) and the crystal 2d spacing you can calculate signal vs. lamda from lamda = 2d*sin(theta). Perhaps you referenced the angle to the crystal surface normal instead?
 
D'oh! Sorry for taking your time, my initial approach was correct but I must have done some silly calculator error.
 

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