First Law of Thermodynamics (Eint = Q-W) question. I am only stuck on part (d)

AI Thread Summary
The discussion revolves around solving a thermodynamics problem using the First Law of Thermodynamics, specifically focusing on the calculation of heat (Q) and work (W) in various paths between states. The user has successfully calculated values for parts (a), (b), and (c) but is struggling with part (d), which requires finding Q for path ib given Eint,b = 27 cal. It is noted that the work from state i to b is equivalent to the work from state i to b to f, where the work from b to f is zero due to constant volume. The final guidance suggests using this relationship to determine Q for path ib.
zag4life
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When a system is taken from state i to state f along path iaf in the figure, Q = 60 cal and W = 10 cal. Along path ibf, Q = 65 cal.
hrw7_18-41.gif

(a) What is W along path ibf? (b) If W = -19 cal for the return path fi, what is Q for this path? (c) If Eint,i = 11 cal, what is Eint,f?(d) If Eint,b = 27 cal what is Q for path ib?(e) For the same value of Eint,b, what is Q for path bf?

Homework Equations


Eint= internal energy of the system; Q= heat; W= work
I have used Eint= Q - W to solve most of the problem.

The Attempt at a Solution


I only am marked wrong on part d which is very frustrating. So far I have:
(a)Wibf = 15 cal because W= Q-E (b) Qfi= -69 cal because Q= -(E)+W (c) Eint,f= 61 cal because Eint,f= Eint+Ei (d) Qib= ? (e) Qbf= 34 because Eint,f =E-Eint,b
Any thoughts?
 
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Hi, zag4life. Welcome to PF.

How does the work for i \rightarrowb compare to the work for i\rightarrowb\rightarrowf?
 
Well, from b to f, because the volume does not change, work is equal to zero. The work for i,b,f would be the same as the work for i,b I think.
 
Good. So, use that to get Q for ib.
 
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