Gibbs free energy various forms

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The discussion centers on the distinctions between ΔG°', ΔG°, and ΔG in thermodynamics. ΔG° represents the Gibbs free energy change at standard conditions, typically defined as 1 atm pressure and a specific temperature, often room temperature. It remains constant across different conditions. In contrast, ΔG varies with changes in conditions such as pressure and temperature. ΔG°' is a modified standard Gibbs free energy that accounts for specific conditions relevant to certain scientific fields, such as a pH of 7 and a temperature of 36 °C. The conversation emphasizes that while ΔG° is a constant, ΔG reflects the actual free energy change under varying conditions, and ΔG°' is a specific case of ΔG° at defined standard conditions.
Raghav Gupta
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What is the difference between 1) ΔG°' and ΔG°
and 2) ΔG°' and ΔG ?
ΔG° I think it is the gibbs free energy at standard state means at room temperature 1 atm pressure.
 
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##\Delta G^0## is constant at all conditions. Its ##\Delta G## that changes with change in conditions.
 
What about ΔG°' ?
 
Where did you read it?
 
It was given in the question of our assignment.
 
May be something like the conditions that are common in your field of science, say pH is 7 and temp is 36 °C.
 
Raghav Gupta said:
What is the difference between 1) ΔG°' and ΔG°
and 2) ΔG°' and ΔG ?
ΔG° I think it is the gibbs free energy at standard state means at room temperature 1 atm pressure.
ΔG0 is the change in free energy between state 1 and state 2, whereState 1: Stoichiometric quantities of pure reactants in separate containers, each at temperature T and 1 atm pressure

State 2: Corresponding stoichiometric quantities of pure products in separate containers, each at temperature T and 1 atm pressure

So ΔG0 is a function of temperature.

Chet
 
He didn't ask about that.
 
Titan97 said:
##\Delta G^0## is constant at all conditions. Its ##\Delta G## that changes with change in conditions.
Alcathous said:
He didn't ask about that.
What do the words "ΔG° I think it is the gibbs free energy at standard state means at room temperature 1 atm pressure." mean to you?

Chet
 
  • #10
I've never seen ΔG0' used before, but, apparently ΔG0' is the value of ΔG0 at 25 C (see post #7).

Incidentally, regarding ΔG, this is the change in free energy if the pressures of the pure species in States 1 and 2 (see post #7) are not all equal to 1 atm.

Chet
 
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