Hole Mass vs Electron Mass: What's the Difference?

In summary, the effective mass of an electron is positive, while the effective mass of a hole is negative.
  • #1
SUVAM ROY
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Why is it opposite to that of an electron?
 
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  • #2
SUVAM ROY said:
Why is it opposite to that of an electron?

Back up a bit. You haven't told us what you already know.

For instance, do you know how we obtain the 'effective mass' of anything in a solid? For example, the "electron" that is in a metal or semiconductor also has an effective mass. Do you know how that is obtained?

In the future, unless you want your question to drag on for people to figure out what exactly you are asking, you must put SOME effort in elaborating your question, but also what you already know and tried to find out. It is required in the PF Rules.

Zz.
 
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  • #3
ZapperZ said:
Back up a bit. You haven't told us what you already know.

For instance, do you know how we obtain the 'effective mass' of anything in a solid? For example, the "electron" that is in a metal or semiconductor also has an effective mass. Do you know how that is obtained?

In the future, unless you want your question to drag on for people to figure out what exactly you are asking, you must put SOME effort in elaborating your question, but also what you already know and tried to find out. It is required in the PF Rules.

Zz.
Well I know what is effective mass, how it's expression is obtained, how it varies for electron with wavenumber 'k' (m* vs k graph). But can't understand why for hole the m* vs k graph is opposite to the graph of electron.
 
  • #4
This is just a matter of reinterpretation: When you remove an electron you can alternatively say that you create a hole and vice versa. Let's say you have n electrons of mass n*m then removing one of it leaves you with mass (n-1)*m. You obtain the same result by saying that you added a hole of mass -m to n*m.
 
  • #5
SUVAM ROY said:
Well I know what is effective mass, how it's expression is obtained, how it varies for electron with wavenumber 'k' (m* vs k graph). But can't understand why for hole the m* vs k graph is opposite to the graph of electron.

Then I don't understand why you have your problem.

For example, look at Page 1 of this link at the top figure of a generic band structure of a semiconductor:

http://users.physik.fu-berlin.de/~pascual/Vorlesung/WS05/Slides/WS05-06%20AdMat%20IT%20-%20L1b.PDF

The bottom of the conduction band (energy band 1), the second derivative of E vs k is positive, and thus, m* is positive. The top of the valence band (energy band 2) has a negative curvature, and thus, the second derivative is negative, giving a negative m*.

Thus, knowing how m* is derived, and knowing the band structure, you get what m* is. If you know these, why are you still having a problem in understanding it?

Zz.
 
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  • #6
ZapperZ said:
Then I don't understand why you have your problem.

For example, look at Page 1 of this link at the top figure of a generic band structure of a semiconductor:

http://users.physik.fu-berlin.de/~pascual/Vorlesung/WS05/Slides/WS05-06%20AdMat%20IT%20-%20L1b.PDF

The bottom of the conduction band (energy band 1), the second derivative of E vs k is positive, and thus, m* is positive. The top of the valence band (energy band 2) has a negative curvature, and thus, the second derivative is negative, giving a negative m*.

Thus, knowing how m* is derived, and knowing the band structure, you get what m* is. If you know these, why are you still having a problem in understanding it?

Zz.
Thanks. It's just my conception was not that clear. Will you check if I am right or not.

While moving through periodic potential when a electron gets attracted towards a positive center(i.e. zero potential area), it can be said that a hole is created in the high potential area where the electron was previously. So, it can be said that the hole got repelled from the zero potential area producing a (-)ve acceleration. So, in a periodic variation of potential hole motion is opposite to the electron motion.So, their effective masses are also opposite.
 
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What is the difference between hole mass and electron mass?

The main difference between hole mass and electron mass is that electrons are negatively charged particles, while holes are positively charged particles in a semiconductor material.

How are hole mass and electron mass measured?

The mass of an electron is measured in units of electron mass (me), while the mass of a hole is measured in units of effective mass (mh*). The effective mass is a measure of the particle's behavior in the material and is influenced by the crystal structure and other factors.

Why is hole mass important in semiconductors?

Hole mass is important in semiconductors because it affects the material's electrical and optical properties. In particular, the effective mass of holes determines their mobility, which is a measure of how easily they can move through the material under an electric field.

How does hole mass affect the performance of electronic devices?

The effective mass of holes can impact the performance of electronic devices in several ways. For example, a higher hole effective mass can lead to lower carrier mobility and slower device operation. On the other hand, a lower hole effective mass can result in higher conductivity and better device performance.

Can hole mass and electron mass be changed or controlled?

While the mass of fundamental particles like electrons cannot be changed, the effective mass of holes can be influenced by the properties of the semiconductor material. By adjusting the material's composition and crystal structure, it is possible to modify the effective mass of holes and thus improve the performance of electronic devices.

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