The polarisation and the direction of propagation are two entirely different issues. The E field is at right angles to the direction of propagation. There is a slight problem here in actually defining the direction of polarisation in terms of H and V. If you have a 'vertically polarised' transmitting antenna then the E field will, indeed be vertical for the wave that is traveling horizontally. If an HP wave is traveling in a horizontal direction, the E field is pointing at right angles to the direction of propagation; that is still horizontal. For a nominally VP wave that is traveling upwards (remember, it is spreading in all directions) at an angle of 45°, the E field, being at right angles to this direction, is not actually vertical but tilted back at 45°. If you fire any linearly polarised signal vertically, however the antenna is orientated, the E field will be horizontal (all lines at right angles to vertical are horizontal). One of the reasons for using circular polarisation for satellite transmissions is that there is no problem distinguishing between clockwise and anticlockwise and there can be no misunderstanding.
I suggest you do a bit more reading a bit less one-to-one questioning now. There is loads of information out there.