Air volume in a closed cylinder increases with temperature according to the ideal gas law, which states that pressure and volume are directly related to temperature. When the temperature rises, the pressure inside the cylinder increases, causing the piston to move until internal pressure equals atmospheric pressure. The relationship can be simplified using Charles' Law, where the ratio of initial and final volumes is proportional to the ratio of initial and final temperatures. Accurate measurements of temperature and understanding the thermodynamic cycle of the Stirling engine are crucial for precise calculations. The discussion emphasizes the need for absolute temperature measurements and the effects of different materials on expansion rates.