How to determine exact differentials

In summary, the conversation discusses the concept of an exact differential and its relation to the equations for dQ and dS. It is noted that while dQ is not an exact differential as a function of V and T, dQ/T is. The conversation also mentions that dQ is an exact differential when V and T are ignored.
  • #1
relativespeak
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I'm not having trouble with the first part, just having trouble understanding why dQ is not exact but dS=dQ/T is. At first I was thinking that it had to do with the V in the dT part of the dQ equation because the single V does not account for changes in V, but this part still exists in the entropy equation. Please help me conceptualize what it means to be an exact differential.
 

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  • #2
hi relativespeak! :smile:
relativespeak said:
… having trouble understanding why dQ is not exact but dS=dQ/T is.

the book is a little misleading :frown:

it means that, as a function of V and T, dQ is not an exact differential, but dQ/T is

of course, if we ignore V ant T, dQ is an exact differential … of Q ! :biggrin:
 
  • #3
What is the differential of a two-variable function?
 

What is an exact differential?

An exact differential is a mathematical concept used in physics and engineering to describe a quantity that can be measured or predicted with complete precision. It is a function that represents the change in a physical quantity, such as position, temperature, or pressure, as a result of infinitesimal changes in other physical quantities.

How do you determine if a differential is exact?

To determine if a differential is exact, you can use the partial derivative test. This involves taking partial derivatives of the function with respect to each variable and checking if they are equal. If they are equal, the differential is exact. Another method is to check if the differential satisfies the condition of being a closed form, meaning that the total differential is equal to zero.

What is the significance of exact differentials?

Exact differentials are significant in physics and engineering because they represent quantities that can be measured or predicted with complete precision. They also help in solving differential equations, which are used to describe the behavior of many physical systems.

What is the relationship between exact differentials and conservative vector fields?

Exact differentials are closely related to conservative vector fields. In fact, a vector field is conservative if and only if its differential is exact. This means that conservative vector fields have potential functions, which are exact differentials, and can be used to represent the work done by a force.

How are exact differentials used in thermodynamics?

In thermodynamics, exact differentials are used to represent the changes in state variables, such as temperature, pressure, and volume, in a system. This allows for the calculation of work and heat transfer in thermodynamic processes. Exact differentials also play a crucial role in the first and second laws of thermodynamics.

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