How to determine exact differentials

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SUMMARY

The discussion centers on the distinction between exact and inexact differentials in thermodynamics, specifically addressing why dQ is not an exact differential while dS = dQ/T is. Participants clarify that dQ, as a function of volume (V) and temperature (T), does not meet the criteria for exactness, whereas the entropy differential dS, derived from dQ, is exact when divided by T. This highlights the importance of understanding the conditions under which differentials are classified as exact or inexact.

PREREQUISITES
  • Understanding of thermodynamic concepts, specifically differentials.
  • Familiarity with the first and second laws of thermodynamics.
  • Knowledge of functions of multiple variables in calculus.
  • Basic grasp of entropy and its relation to heat transfer.
NEXT STEPS
  • Study the mathematical definition of exact differentials in calculus.
  • Explore the implications of the first and second laws of thermodynamics on heat and work.
  • Learn about the derivation and significance of the entropy formula dS = dQ/T.
  • Investigate the role of state functions in thermodynamic processes.
USEFUL FOR

Students of thermodynamics, physics enthusiasts, and anyone seeking to deepen their understanding of exact and inexact differentials in the context of heat transfer and entropy.

relativespeak
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I'm not having trouble with the first part, just having trouble understanding why dQ is not exact but dS=dQ/T is. At first I was thinking that it had to do with the V in the dT part of the dQ equation because the single V does not account for changes in V, but this part still exists in the entropy equation. Please help me conceptualize what it means to be an exact differential.
 

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hi relativespeak! :smile:
relativespeak said:
… having trouble understanding why dQ is not exact but dS=dQ/T is.

the book is a little misleading :frown:

it means that, as a function of V and T, dQ is not an exact differential, but dQ/T is

of course, if we ignore V ant T, dQ is an exact differential … of Q ! :biggrin:
 
What is the differential of a two-variable function?
 

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