How was the Birch-Murnaghan equation derived for high pressure volume behavior?

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SUMMARY

The Birch-Murnaghan equation, essential for modeling volume behavior under high pressures exceeding 1 GPa, is derived from principles outlined in Birch's 1947 paper, “Finite Elastic Strain of Cubic Crystals,” published in Physical Review. Key parameters include Vo, the volume at ambient pressure, Bo, the bulk modulus, and B’, its pressure derivative. The derivation is isothermal, and additional resources, such as the PDF found at https://mcbrennan.github.io/BMderivation.pdf, provide further insights into the mathematical formulation.

PREREQUISITES
  • Understanding of the Birch-Murnaghan equation
  • Familiarity with bulk modulus and its derivatives
  • Knowledge of isothermal processes in thermodynamics
  • Basic principles of elastic strain in cubic crystals
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  • Review Birch's original paper, “Finite Elastic Strain of Cubic Crystals,” for foundational concepts
  • Study the derivation of the Birch-Murnaghan equation in detail using the provided PDF
  • Explore the implications of isothermal conditions on material behavior under pressure
  • Investigate applications of the Birch-Murnaghan equation in materials science and geophysics
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Physicists, materials scientists, and researchers focusing on high-pressure physics and the elastic properties of materials will benefit from this discussion.

Sylvester
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Hello, physicists! Does anyone know how was this equation (below) mathematically derived? It is basically used to describe the behavior of volume at very high pressures (above 1 GPa). Vo designates the volume at ambient pressure. Bo is the bulk modulus and B’ its pressure derivative. I can't find anything in the literature where there is a step-by-step or at least a clue on how to come up with this expression.
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I found this with google
https://mcbrennan.github.io/BMderivation.pdf

I would guess that Birch‘s paper has a derivation
Birch,F., “Finite Elastic Strain of Cubic Crystals,” Physical Review 71 (11),809–824 (1947).

Notice that it is isothermal.
 
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Frabjous said:
I found this with google
https://mcbrennan.github.io/BMderivation.pdf

I would guess that Birch‘s paper has a derivation
Birch,F., “Finite Elastic Strain of Cubic Crystals,” Physical Review 71 (11),809–824 (1947).

Notice that it is isothermal.
Hey Frabjous! Thanks for the material. Just now, I briefly checked the pdf file and I think that's more than enough. Again, thank you so much for the help!
 
Sylvester said:
Hey Frabjous! Thanks for the material. Just now, I briefly checked the pdf file and I think that's more than enough. Again, thank you so much for the help!
You are welcome.

BTW, I could be wrong, but I think F is the Helmholtz free energy, not force.
 
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