When connecting two ideal cells with different EMFs, such as 6 volts and 3 volts, in parallel, the net EMF cannot be simply determined due to the implications of internal resistance. It is impractical to label them as ideal cells since internal resistance must be considered when no external resistance is present. Additionally, ideal voltage sources with differing voltages cannot be connected in parallel without violating their definitions. The discussion highlights that while ideal components are useful in introductory electronics, real-world applications require consideration of internal resistances. Ultimately, understanding these principles is crucial for accurate circuit analysis.