Is it a ionic or a covalent bond?

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For the Tollens' reagent, the Ag-N bond is dative covalent, meaning that the nitrogen donates both electrons to the silver ion. This allows the silver ion to be reduced and form a mirror on the surface of the reaction vessel. In summary, the C-Mg bond in the Grignard reagent is mostly covalent, while the NH3-Ag+ bond in Tollens' reagent is a dative covalent bond. The Mg-Cl bond in the Grignard reagent is covalent, but the Mg-CH3 bond is ionic, and the Ag-N bond in Tollens' reagent is also dative covalent. These bonds play important roles
  • #1
jaumzaum
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In the compunds below, are the bonds most ionic or covalent?

CH3-Mg-Cl (Grignard reagent), C-Mg bond

[Ag(NH3)2]+ (Tollens' reagent), Ag-N bond

Thanks
John
 
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  • #2
For the Grignard reagent bond, C-Mg, I think it is covalent mostly. The electronegativity difference between C-Mg is not too significant. But it will be polar certainly.

For the Tollen's reagent, the bond between NH3 and Ag+ is that of dative covalent, because NH3 can be considered as ligand to Ag+
 
  • #3
For the Grignard reagent, the Mg-Cl bond is covalent, but the Mg-CH3 bond is ionic with the carbon carrying the negative charge and the Mg-Cl carrying the positive charge. This allows the lone pair on the carbanion to attack sites on other molecules containing a partial positive (such as carbonyls).
 

1. What is the difference between an ionic and a covalent bond?

An ionic bond is a type of chemical bond formed between two atoms when one atom donates its valence electrons to the other atom, resulting in the formation of positively and negatively charged ions. A covalent bond, on the other hand, is a type of chemical bond formed when two atoms share one or more pairs of electrons.

2. How can I determine if a bond is ionic or covalent?

The easiest way to determine if a bond is ionic or covalent is to look at the electronegativity difference between the two atoms involved. If the electronegativity difference is greater than 1.7, the bond is considered ionic. If the electronegativity difference is less than 1.7, the bond is considered covalent.

3. What types of elements typically form ionic bonds?

Ionic bonds are typically formed between a metal and a nonmetal. Metals tend to have low electronegativity, meaning they are more likely to donate electrons, while nonmetals tend to have high electronegativity, meaning they are more likely to accept electrons.

4. Can a bond be both ionic and covalent?

Yes, some bonds can exhibit both ionic and covalent characteristics. This is known as a polar covalent bond. In polar covalent bonds, the electrons are not shared equally between the two atoms, resulting in a slight positive and negative charge on each atom.

5. How does the strength of an ionic bond compare to the strength of a covalent bond?

Generally, ionic bonds are stronger than covalent bonds. This is because ionic bonds involve the attraction between oppositely charged ions, which are held together by strong electrostatic forces. Covalent bonds, on the other hand, involve the sharing of electrons, which are held together by weaker forces.

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