Is an Ice/Water Mixture Preferred Over Pure Ice in the Crystallization Process?

In summary, in the crystallization process, an ice/water mixture is sometimes used as a bath instead of pure ice after gravity filtration is carried out. This is because the ice/water mixture allows for better contact between the liquid and the flask, leading to more efficient cooling. Sometimes, salts are added to the ice/water bath to achieve a colder temperature of around -3C. This method is preferred in applications where the liquid has a higher freezing point. In distillation, an isopropanol-water ice bath can be used to slow corrosion and achieve very low temperatures.
  • #1
Soaring Crane
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In the crystallization process after gravity filtration is carried out, a mixture of ice and water is sometimes used as a bath instead of just ice. I know that the ice/water bath can be used to cool the filtrate to around 0 C while just crushed ice or an ice-salt bath may cool the filtrate to below 0 C. An ice/water mixture instead of pure ice is used so that the solution does not ultimately freeze?? (Are there any examples where one is preferred over another?)

Thank you.
 
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  • #2
It is usually because there is better contact between the liquid and the flask in an ice/water bath. An ice bath would only contact the flask in spots.
 
  • #3
sometimes they add salts to the icewater bath to get it colder around -3C and the better efficency at cooling because more surface is contacted
it depends what application is used but the freezing is not usually a problem unless you have a pure liquid with a higher freezing point. in distillation sometimes they use an isopropanol water ice bath to slow the corrosion of metal parts and it gets very cold
 

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