rhody said:
1. Does #3 have a special design to accommodate the MOX fuel ?
2. Does the MOX fuel heat faster, and cool slower, both in the reactor and in the spent fuel pools ?
3. If exposed to the air due to melting, what additional elements and in what quantities and toxicity from the MOX are released to the environment ?
1) Unit #3 does not have a special design. MOX fuel is designed to behave like a UO
2 assembly from a thermal standpoint. As I understand the available data, Unit 3 had 32 MOX assemblies - and probably not all fuel rods were MOX. They were part of a larger reload of on the order of 140-160 assemblies. One quarter of the core of 548 assemblies is 137, and they may reload slightly more or less depending on cycle length, capacity factor, and residual reactivity in the fuel. The MOX fuel can be placed in uncontrolled cells such that shutdown margin is not reduced.
Regarding
Wikipedia article said:
As plutonium isotopes absorb more neutrons than uranium fuels, reactor control systems may need modification.
MOX fuel tends to run hotter because of lower thermal conductivity, which may be an issue in some reactor designs.
PuO
2 and TU elements are dispersed in a UO
2 matrix. The portion of PuO
2 can be adjusted to an equivalence with a UO
2 assembly.
The thermal conductivity is slightly less than UO
2, but I don't consider that significant. One can design to control the power peaking. Fuel designers understand the difference between MOX and UO
2, so they can design to mitigate the effect of these differences.
The decay heat of MOX at a given burnup is slightly higher than UO
2, but that's not significant. After several months, I don't see the difference in decay heat being an issue.
2) MOX fuel may produce slightly more Xe, but less Kr, than UO
2 fuel at a given burnup. This fission gas release (Xe, Kr) from the fuel into the internal void volume may be slightly higher, but it's not significant IMO. See the attached figure for a comparison of fission product yields from thermal fissioning of U-235 and Pu-239.
3) The concern about MOX is due to the Pu istopes and transuranics (TU, or isotopes of Am, Cm) which are higher in MOX than UO
2 at the same burnup. The concern about fires involving nuclear fuel relates to the notion that some fuel particles may be released as aerosols and dispersed. A dispersed aerosol would increase the likelihood that folks could ingest or inhale the fuel particles. However, it is not clear to me that this is happening at Fukushima. Anytime there is a fuel failure, there is a concern about fuel particles escaping from the fuel rods and depositing within the reactor building.
Aside from U, Pu and other TU elements, the release of fission products from the fuel to the environment is a serious concern, regardless of the initial fuel matrix, e.g., MOX or UO
2.
Thanks in advance...
BTW, good job Borek, in keeping this thread on track, amazing that it has this many responses and for the most part has been trying to present accurate information, a credit to all who are doing their best to present accurate, timely information.
Rhody...
Thanks, Borek!