Astronuc
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Boric acid is NOT normally used in a BWR - certainly not in the primary system - and not in the spent fuel pool. The spent fuel structure contains boron in boral or boraflex.fluutekies said:I think I got it:
Under normal conditions enriched boric acid H3BO3 probably is -even at its much higher price and limited availability- the boron compound of choice in a nuclear power plant: highest concentration B-10, lowest concentration of accompanying elements (only O and H) and high purity due to its multi-step synthesis. And indeed therefore less high-grade NaOH or other base is needed for pH-adjustment.
I assume the purity requirements of the cooling water are very stringent. If the water after refueling/maintenance has to be made boron-free again by ion-exchange, smaller quantities are advantageous, even if the materials are more expensive.
Soluble boron in a BWR is introduced only in the case of emergency.
Soluble boron is used routinely in PWRs, and some used enriched boric acid. Some fuel design use enriched boron in ZrB2 coating on fuel pellets in some fraction of fuel rods.