Lowering of Vapour Pressure - a C.P ?

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Lowering of vapor pressure is confirmed as a colligative property, as demonstrated through the equation Pa = Poaχa, where Pa represents the vapor pressure of the solution, Poa is the vapor pressure of the pure solvent, and χa is the mole fraction of the solvent. By substituting χa with (1-χb), it is shown that the lowering of vapor pressure is directly proportional to the number of moles of solute in dilute solutions. However, there is a distinction made in some literature, stating that while relative lowering of vapor pressure is a colligative property, the absolute lowering of vapor pressure may not be classified as such. Additionally, a request for free reaction simulation software, similar to Aspen Plus, was made in the discussion.
zorro
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Is lowering of vapour pressure a colligative property?

I tried proving this and found it to be true.

Pa = Poaχa, where a=solvent and b=solute

Substituting χa=1-χb and some rearranging, we get

Poa-Pa=Poaχb

As Poa is constant for a given liquid at a given temperature, lowering of vapour pressure (LHS) is directly proportional to the no. of moles of solute provided the solution is very dilute.

Is my proof correct?
 
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Hi
your proof is correct
right lowering of vapour pressure really is a colligative property
 
But my book says that Relative lowering of vapour pressure is a colligative property but lowering of vapour pressure is not a colligative property.
 
hi,

can anyone tell me where i can get a free reaction simulation software, like aspen plus.

thanks.
 
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