Partition function for electrons/holes

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SUMMARY

The discussion focuses on deriving the single particle partition functions for electrons and holes in a semiconductor at temperature T and volume V. The partition functions, Ze(1) and Zh(1), are expressed using the formula Z(1) = (V/λ^3), where λ is the thermal wavelength defined as λ = h/√(2πmkT). The derivation involves integrating over momentum space, accounting for the density of states, and recognizing that each energy eigenstate has two spin states for electrons.

PREREQUISITES
  • Understanding of statistical mechanics and partition functions.
  • Familiarity with semiconductor physics, particularly electron and hole dynamics.
  • Knowledge of thermal wavelength calculations in quantum mechanics.
  • Basic proficiency in calculus for integration over momentum space.
NEXT STEPS
  • Study the derivation of partition functions in statistical mechanics.
  • Explore the concept of excitons and their formation in semiconductors.
  • Learn about the implications of electron-hole plasma in semiconductor devices.
  • Investigate the role of spin states in quantum statistical mechanics.
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This discussion is beneficial for physicists, materials scientists, and students studying semiconductor physics and statistical mechanics, particularly those interested in the behavior of charge carriers in semiconductors.

Welshy
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Homework Statement


By shining and intense laser beam on to a semiconductor, one can create a collection of electrons (charge -e, and effective mass me) and holes (charge +e, and effective mass mh) in the bulk. The oppositely charged particle may pair up (as in a hydrogen atom) to form a gas of excitons, or they may dissociate into an electron hole plasma.

a) Write down the single particle partition functions Ze(1) and Zh(1) at temperature T in a volume V for electrons and holes respectively. (The thermal wavelength \lambda for a particle is \lambda = \frac{h}{\sqrt{2 \pi mkT}}

Homework Equations

The Attempt at a Solution


I know that the partition function is exp[-E/kT] summed over all energies or integrated with a density of states over all energies. But how do I go about it in this case?
 
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In our notes somewhere (section 11/12/13), you can see that he uses the equation:

Z(1) = (V/λ^3), where V is the volume.

I'm not sure where it comes from, but I think we just need to learn it.
 
You can obtain that formula by summing over all the energy states by approximating the summation by an integral using the fact that the number of quantum states within a volume V_p of momentum space is

V V_p/h^3

So, if you integrate over all momenta, the energy is E = p^2/(2m) and you can write:

Z1 = Integral of V d^3p/h^3 exp[-beta p^2/(2m)] =

V/h^3 Integral from |p| = 0 to infinity of 4 pi p^2
exp[-beta p^2/(2m)] d|p|

For electrons you must multiply this by 2 because there are two spin states for each energy eigenstate.
 

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